Trent University Graduate Thesis Collection

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    Copyright for all items in the Trent University Graduate Thesis Collection is held by the author, with all rights reserved, unless otherwise noted.
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    Surface-Initiated Polymerization Carbon Substrate: Polymer Brush Optimization and Adsorption of Naphthenic Acids in OSPW

    Year: 2026, 2026
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Carr, Teagan A, Thesis advisor (ths): Vreugdenhil, Andrew J, Degree committee member (dgc): Zenkina, Olena V, Degree committee member (dgc): Katz, Michael J, Degree committee member (dgc): Stewart, Kate, Degree granting institution (dgg): Trent University
    Abstract: <p>This thesis presents the design, synthesis, and evaluation of activated carbon polyacrylamide (AC-PAM) composites for oil sands tailings remediation, integrating flocculation and adsorption functionalities. Surface-initiated atom transfer radical polymerization (SI-ATRP) was employed to graft high molecular weight PAM brushes onto petroleum coke and commercial activated carbon, with SARA… more

    Controlling the Radical Polymerization of Polyacrylamide from the Surface of Activated Carbon for Flocculation Applications

    Year: 2025, 2025
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Reyes, Kyle Matthew Dabu, Thesis advisor (ths): Vreugdenhil, Andrew J, Degree committee member (dgc): Keske, Eric, Degree committee member (dgc): Zenkina, Olena V, Degree committee member (dgc): Adronov, Alex, Degree granting institution (dgg): Trent University
    Abstract: <p>The oil sands industry is producing large volumes of tailings waste reaching 2 billion cubic meters by 2034 In this study, the industrial standard flocculant, high molecular weight PAM, was grafted from the surface of activated carbon (AC). This material was designed to increase the flocculant's hydrophobicity and density. Different molecular weight PAM was grafted from AC with… more

    N-Heterocyclic Carbenes: Studies in Metallation, Ligand Modification, and Property Determination

    Year: 2025, 2025
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Lim, Meilin, Thesis advisor (ths): Keske, Eric C, Degree committee member (dgc): Vreugdenhil, Andrew J, Degree committee member (dgc): Zenkina, Olena V, Degree committee member (dgc): Singer, Robert D, Degree granting institution (dgg): Trent University
    Abstract: <p>N-Heterocyclic Carbenes (NHCs) have significantly impacted organometallic chemistry as ligands in transition metal catalysis, offering strong electron-donating properties and high bond dissociation energies. However, their structural versatility is limited by the scarcity of commercial precursors and challenging modification procedures. Furthermore, we have investigated its coordination… more