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Study of Aerosols for use in Water Remediation of Pharmaceutical Pollutants
In this thesis, aerosolization was studied as a possible means of water remediation for several environmentally relevant pharmaceutical pollutants, known for their persistence in wastewater effluent and potable water sources. Seven different pharmaceutical compounds and a well-known plasticizer were all shown to decrease considerably in concentration in aerosol that was produced and subsequently collected within a short time span. Strong evidence is presented that an enhanced rate of partitioning into the gas phase at the air-water interface of water droplets exists for every compound tested relative to that occurring in bulk solution. UV photolysis in aerosols was also explored and shown for sulfamethoxazole to be at least an order of magnitude faster in aerosols then in bulk solution. The implications towards both the environmental fate, and removal of these compounds from water sources is discussed.
Author Keywords: Aerosols, Air-water partitioning, Pharmaceuticals, Photolysis, Sulfamethoxazole
Anthropogenic microfibres in background natural environments in Ireland
Microfibres, which are threadlike particles < 5 mm, are the most common type of microplastic reported in the environment. However, few studies have focused on their abundance in background natural environments. This study assessed the abundance of microfibres in rainfall samples (from four precipitation monitoring stations) and across three headwater lake catchments that were in remote, undeveloped areas, away from anthropogenic disturbance and anthropogenic emission sources (i.e., sites were background natural environments). Anthropogenic microfibres were observed in all samples using visual identification methods, with Raman spectroscopy confirming the presence of polyester film and synthetic pigments, e.g., indigo and hostasol green. The estimated annual average atmospheric deposition of microfibres was ~28,800 mf m-2. Meteorological variables, e.g., rain, wind direction, and relative humidity were correlated with the abundance of microfibres. The average abundance of microfibres in headwater lake catchments was 24 mf g-1 in moss, 0.70 mf m-3 in surface trawl, 9,690 mf m-3 in subsurface, 910 mf kg-1 in lake sediment and 576 mf kg-1 in lakeshore sediment.
Author Keywords: Atmospheric Deposition, Background Environments, Headwater Lake Catchments, Microfibres, Microplastics, Rainfall
An Emergent Model of the Return to Learn Process for Adolescents with Prolonged Concussion
Current literature on concussion management focuses primarily on the return to physical activity, while the return to learn process is less clearly understood. This knowledge gap is particularly problematic for adolescents, whose primary responsibility is academics. The present study sought to develop a more in-depth understanding of the return to learn process through the perspectives of adolescents who had sustained a concussion and their parents in in-person, semi-structured interviews. A substantive grounded theory of the return to learn process for adolescents that emerged from the data is provided. The basic model is consistent with many speculative, non-empirically based concussion management protocols, but extends these models by emphasizing the central role of parents in managing their child's recovery process, highlighting the importance of role fulfillment within the concussion management network, and identifying the impact of the adolescent's capacity and readiness for help-seeking. The results also highlight the vulnerability of concussed adolescents to losing their support structure as they move through key school transitions. Implications for educators, medical professionals, parents, and adolescents in the return to learn process are also discussed.
Author Keywords: Adolescent, Concussion, Concussion Management, Multidisciplinary Management, Return to Learn, Return to School
Canoeing through Resurgence: Wiigwaas Jiimaan and Cultural Resurgence within n'Daki Menan
Anishinabai are jiimaan people. The traditional building of wiigwaas jiimaan is a part of a resurgence project that is restoring and maintaining cultural connection to our homelands, the water, and community members. An approach to cultural resurgence, such as the wiigwaas jiimaan, is an attempt to generate a better connection to our homeland, self- determination, and forms of healing within a cultural context. Through diverse research methodologies, this project will open new doors to cultural resurgence methods, Indigenous knowledge and the story telling of the wiigwaas jiimaan.
Over the summer of 2018, I built a wiigwaas jiimaan in my home community of Temagami First Nation. It is from this experience that this research shaped. Through the approach of storytelling to my reflective notes, while incorporating an Indigenous knowledge and resurgence methodology. It is important that when you are reading this, that you keep an open mind, sit comfortably and enjoy the interweaving of story and research. The thesis creates a better understanding of resurgence practices, the history of the Teme- Augama Anishinabai, my story and experience with the wiigwaas jiimaan, and the rebuilding of my community through this cultural initiative. Moving forward I hope that this research continues and evolves to other communities, who look for healing and cultural reclaiming through the land. Miigwetch.
Author Keywords: Culture, Healing, Land-Based, Resurgence, Temagami First Nation, Wiigwaas jiimaan
When He Reigns, It Pours: The Use of Water Rituals and Water Symbolism by the Royal Court of Bagan From the 11th to the 14th Century
This thesis examines the symbolic meaning and significance that the elite attached to water in ancient Bagan. Through the use of ethnoarchaeological, epigraphic, archaeological, and iconographic data, this study examines the role of water as part of rituals performed by the royal court and the ways in which the royalty of Bagan, in particular King Kyansittha, negotiated, appropriated and disseminated water symbolism to fulfill his interests. Data indicates that the symbolic and religious meaning of water was intricately attached to Buddhist concepts of fertility, wisdom, creativity, and protective powers. Evidence suggests that the royalty employed different techniques to appropriate and disseminate water ritualization, including the performance of water rituals that were closely attached to kingship, power, and ruler legitimacy, the promotion of an alliance with creatures capable of increasing rains and fertility, and the use of analogies that compared the properties of water with the virtues of the king.
Author Keywords: Bagan, Bagan Iconography, Jataka Tales, Royal Rituals, Theravada Buddhism, Water Rituals
Cytokinins in nematodes: the potential role of cytokinins in soybean (Glycine max) resistance to soybean cyst nematode (Heterodera glycines)
To investigate cytokinins (CKs) in nematodes, CK profiles of a free-living Caenorhabditis elegans and a plant parasitic Heterodera glycines (soybean cyst nematode, SCN) were determined at the egg and larval stages. SCN had higher total CK level than C. elegans; however, CKs in SCN were mostly inactive precursors, whereas C. elegans had more bioactive forms. This is the first study to show that methylthiols are present in nematodes and may affect plant infection. In infectious SCN larvae, methylthiol levels were much higher than in eggs or C. elegans larvae. Furthermore, The CK profiles of SCN-susceptible and resistant Glycine max cultivars at three developmental stages revealed that, regardless of the resistance level, SCN infection caused an increase in root CKs. One resistant cultivar, Pion 93Y05, showed significantly high levels of bioactive N6-isopentenyladenine (iP) in the non-infected roots which indicated a potential role of CKs in soybean resistance to SCN.
Author Keywords: Cytokinins, HPLC-MS/MS, Nematode, SCN resistance, Soybean
Virtual Voices: A comparison of Rehabilitative Care Alliance (RCA) focus group findings and survey results on rehabilitative care needs after hip fracture. Contributing to the co-design of rehabilitative care with persons and families.
A consistent provincial approach to capacity planning for rehabilitative care had been
identified as a critical gap in the field of health care in Ontario (Rehabilitative Care
Alliance, 2015a). In response, the rehabilitative care alliance (RCA) developed a needs
based hip fracture capacity planning canvas together with persons and families. This
research utilized computer assisted participation (CAP) to gather additional perspectives
from Virtual Voices via an on-line survey. The results of the Virtual Voices survey were
compared to Ontario's RCA hip fracture patient focus group findings. CAP facilitated
more voices and more ideas through virtual engagement. The survey method required
97% (10.6 hours) less time than the focus group. The Virtual Voices respondents
provided validation of the focus groups' confirmation of the rehabilitative care needs,
locations and most core team members as well as identified new ideas. The results
support the implementation of a needs-based capacity plan that enables individualized
care planning. This research provides a blueprint for the ongoing engagement of
persons and families in the co-creation of a sustainable rehabilitative care system. A
dashboard and e-health app would enable ongoing co-design, monitoring and
evaluation.
Author Keywords: Computer Assisted Participation (CAP), Computer Assisted Survey, Hip Fracture, Rehabilitative Care Needs, Virtual Collaboration, Virtual Engagement
The Student's Bell Tower: The Legacy of the University of Regina's The Carillon in the Digital Age
The university newspaper is a vital aspect of the university public, as it provides a platform for students to voice their opinions on topics pertaining to the culture of their university and gives students critical information about what is happening on campus. This thesis uses the University of Regina's The Carillon as a case study to evaluate how university newspapers interact with and influence their publics. In Chapter One, I detail the history of The Carillon, and how the radical atmosphere of the 1960s influenced the newspaper's growth. In Chapter Two, I explore how The Carillon uses facets of digitality—such as their website, multimedia, and social media—to increase its readership. The chapter examines how these digital platforms reach The Carillon's publics more efficiently, but still adhere to the traditions established by the newspaper from its inception. Finally, in Chapter Three, I assess the success of university newspapers which have transitioned to a strictly digital presence. For this assessment, I use the University of Alberta's The Gateway and the University of Prince Edward Island's The Cadre as case studies, and argue that The Carillon can learn from these digital newspapers to become more effective in using digital media to reach its student public. Altogether, this study of university newspapers offers a guide on how to maintain a balance between materiality and digitality, while also preserving the university newspaper's legacy and traditions.
Author Keywords: Digitality, Journalism, Materiality, Publics, The Carillon, University Newspapers
Historic Magnetogram Digitization
The conversion of historical analog images to time series data was performed by using deconvolution for pre-processing, followed by the use of custom built digitization algorithms. These algorithms have been developed to be user friendly with the objective of aiding in the creation of a data set from decades of mechanical observations collected from the Agincourt and Toronto geomagnetic observatories beginning in the 1840s. The created algorithms follow a structure which begins with pre-processing followed by tracing and pattern detection. Each digitized magnetogram was then visually inspected, and the algorithm performance verified to ensure accuracy, and to allow the data to later be connected to create a long-running time-series.
Author Keywords: Magnetograms
Social Anxiety and Emotional Competence: A 15 Year Follow-up Study
Prior research has examined social anxiety, emotional competence (EC) and life adjustment (i.e., loneliness and life satisfaction) using cross-sectional designs, although there is limited information on their association over time. The present study examined the impact of social anxiety on life adjustment and assessed if EC could mediate this relationship from young to middle adulthood. University students (N = 283) completed self-report measures at two time points: in first year university and 15 years later. The results accord with previous research demonstrating the stability and slight decrease of social anxiety over time. Social anxiety in young adulthood was a robust predictor of loneliness in middle adulthood, and a weak predictor of life dissatisfaction for men. Mediation analyses revealed that social anxiety was indirectly associated with interpersonal adjustment via EC, especially the intrapersonal EC domain. Social anxiety requires early intervention and EC may help to prevent later social anxiety and maladjustment.
Author Keywords: emotional intelligence, life adjustment, social anxiety