Year: 2025, 2025
Member of: Trent University Graduate Thesis Collection
Name(s): Creator (cre): Lim, Meilin, Thesis advisor (ths): Keske, Eric C, Degree committee member (dgc): Vreugdenhil, Andrew J, Degree committee member (dgc): Zenkina, Olena V, Degree committee member (dgc): Singer, Robert D, Degree granting institution (dgg): Trent University Abstract: <p>N-Heterocyclic Carbenes (NHCs) have significantly impacted organometallic chemistry as ligands in transition metal catalysis, offering strong electron-donating properties and high bond dissociation energies. However, their structural versatility is limited by the scarcity of commercial precursors and challenging modification procedures. Furthermore, we have investigated its coordination… more Year: 2024, 2024
Member of: Trent University Graduate Thesis Collection
Name(s): Creator (cre): Brick, Kasandra Julie Anne, Thesis advisor (ths): Keske, Eric C, Degree committee member (dgc): Maly, Kenneth, Degree committee member (dgc): Zenkina, Olena, Degree committee member (dgc): Vreugdenhil, Andrew, Degree granting institution (dgg): Trent University Abstract: <p>The synthesis of biaryls through transition metal catalyzed cross-coupling reactions has been instrumental for synthetic organic chemists. The Hiyama reaction, which features organosilicon derived cross-coupling partners with aryl chlorides, remains relatively underdeveloped compared to other cross-coupling reactions. In this thesis, it is demonstrated that bench stable Palladium N-… more Full Text: PALLADIUM N-HETEROCYCLIC CARBENE COMPLEXES IN CROSS-COUPLING REACTIONS: LIGAND AND CATALYST DEVELOPMENT A Thesis Submitted to the Committee of Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Master of Science in the Faculty …
Year: 2024, 2024
Member of: Trent University Graduate Thesis Collection
Name(s): Creator (cre): Brick, Kasandra Julie Anne, Thesis advisor (ths): Keske, Eric C, Degree committee member (dgc): Maly, Kenneth, Degree committee member (dgc): Zenkina, Olena, Degree committee member (dgc): Vreugdenhil, Andrew, Degree granting institution (dgg): Trent University Abstract: <p>The synthesis of biaryls through transition metal catalyzed cross-coupling reactions has been instrumental for synthetic organic chemists. The Hiyama reaction, which features organosilicon derived cross-coupling partners with aryl chlorides, remains relatively underdeveloped compared to other cross-coupling reactions. In this thesis, it is demonstrated that bench stable Palladium N-… more
