Year: 2016, 2016
Member of: Trent University Graduate Thesis Collection
Name(s): Creator (cre): Shetranjiwalla, Shegufta, Thesis advisor (ths): NARINE, SURESH S, Thesis advisor (ths): Vreugdenhil, Andrew, Degree committee member (dgc): Metcalfe, Chris, Degree committee member (dgc): Dawson, Peter, Degree granting institution (dgg): Trent University Abstract: <p>Thermoplastic poly(ester urethane)s (TPEU)s derived from vegetable oils possess inferior physical properties compared to their entirely petroleum-based counterparts due to the structural limitations and lower reactivity of the precursor lipid-derived monomers. The present work shows that high molecular weight of TPEUs with enhanced performance can be obtained from lipid-derived monomers… more Full Text: Lipid-derived Thermoplastic Poly(ester urethane)s: Effect of Structure on Physical Properties A Dissertation Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy in the Faculty of …
Year: 2016, 2016
Member of: Trent University Graduate Thesis Collection
Abstract: <p>The present thesis explores the cold flow properties of biodiesel and the effect of vegetable oil derived compounds on the crystallization path as well as the mechanisms at play at different stages and length scales. Model systems including triacylglycerol (TAG) oils and their derivatives, and a polymer were tested with biodiesel. The goal was to acquire the fundamental knowledge that… more Full Text: MITIGATING COLD FLOW PROBLEMS OF BIODIESEL: STRATEGIES WITH ADDITIVES A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Doctor of Philosophy in the Faculty of Arts and Science TRENT UNIVERSITY …
Year: 2016, 2016
Member of: Trent University Graduate Thesis Collection
Abstract: <p>This thesis explores the use of 1-butene cross metathesized palm oil (PMTAG) as a feedstock for preparation of polyols which can be used to prepare rigid and flexible polyurethane foams. PMTAG is advantageous over its precursor feedstock, palm oil, for synthesizing polyols, especially for the preparation of rigid foams, because of the reduction of dangling chain effects associated with… more Full Text: Synthesis of Lipid Based Polyols from 1-butene Metathesized Palm Oil for Use in Polyurethane Foam Applications A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Doctor of Philosophy in the Faculty …
Year: 2016, 2016
Member of: Trent University Graduate Thesis Collection
Abstract: <p>Structure-property relationships are increasingly valued for the identification of specifically engineered materials with properties optimized for targeted application(s). In this work, linear and branched diesters for use in lubricant formulations are prepared from lipid-based oleochemicals and their structure-property relationships reported. It is shown that the branched diesters… more Full Text: NOVEL ALIPHATIC LIPID-BASED DIESTERS FOR USE IN LUBRICANT FORMULATIONS: STRUCTURE PROPERTY INVESTIGATIONS A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy in the …
