Year: 2024, 2024
Member of: Trent University Graduate Thesis Collection
Name(s): Creator (cre): Brick, Kasandra Julie Anne, Thesis advisor (ths): Keske, Eric C, Degree committee member (dgc): Maly, Kenneth, Degree committee member (dgc): Zenkina, Olena, Degree committee member (dgc): Vreugdenhil, Andrew, Degree granting institution (dgg): Trent University Abstract: <p>The synthesis of biaryls through transition metal catalyzed cross-coupling reactions has been instrumental for synthetic organic chemists. The Hiyama reaction, which features organosilicon derived cross-coupling partners with aryl chlorides, remains relatively underdeveloped compared to other cross-coupling reactions. In this thesis, it is demonstrated that bench stable Palladium N-… more Year: 2023, 2023
Member of: Trent University Graduate Thesis Collection
Abstract: <p>The generation of polymer brushes by surface-initiated polymerization techniques has become a powerful tool for the creation of hybrid materials. Governed by the type and amount of polymer used in the modification, the chemical and physical properties of a surface can be tailored by polymer grafting. In this study, a commonly used polymer flocculant, polyacrylamide (PAM), was grafted… more Year: 2021, 2021
Member of: Trent University Graduate Thesis Collection
Name(s): Creator (cre): Scotland, Kevin, Thesis advisor (ths): Vreugdenhil, Andrew J, Degree committee member (dgc): Zenkina, Olena, Degree committee member (dgc): Parnis, Mark, Degree committee member (dgc): Zelisko, Paul, Degree committee member (dgc): Atkinson, Bill, Degree granting institution (dgg): Trent University Abstract: <p>This thesis describes the synthesis, application and evaluation of a UV crosslinked 3-methacryloxypropyltrimethoxysilane-derived coating formulation. This is a two-component sol-gel system with 3-methacryloxypropyltrimethoxysilane (MaPTMS) and tetraethoxysilane (TEOS). Herein we show that if we change the co-solvent required for solubilizing MaPTMS from the more common methanol and… more
