Trent University Graduate Thesis Collection

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    Copyright for all items in the Trent University Graduate Thesis Collection is held by the author, with all rights reserved, unless otherwise noted.
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    Surface-Initiated Polymerization Carbon Substrate: Polymer Brush Optimization and Adsorption of Naphthenic Acids in OSPW

    Year: 2026, 2026
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Carr, Teagan A, Thesis advisor (ths): Vreugdenhil, Andrew J, Degree committee member (dgc): Zenkina, Olena V, Degree committee member (dgc): Katz, Michael J, Degree committee member (dgc): Stewart, Kate, Degree granting institution (dgg): Trent University
    Abstract: <p>This thesis presents the design, synthesis, and evaluation of activated carbon polyacrylamide (AC-PAM) composites for oil sands tailings remediation, integrating flocculation and adsorption functionalities. Surface-initiated atom transfer radical polymerization (SI-ATRP) was employed to graft high molecular weight PAM brushes onto petroleum coke and commercial activated carbon, with SARA… more

    Controlling the Radical Polymerization of Polyacrylamide from the Surface of Activated Carbon for Flocculation Applications

    Year: 2025, 2025
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Reyes, Kyle Matthew Dabu, Thesis advisor (ths): Vreugdenhil, Andrew J, Degree committee member (dgc): Keske, Eric, Degree committee member (dgc): Zenkina, Olena V, Degree committee member (dgc): Adronov, Alex, Degree granting institution (dgg): Trent University
    Abstract: <p>The oil sands industry is producing large volumes of tailings waste reaching 2 billion cubic meters by 2034 In this study, the industrial standard flocculant, high molecular weight PAM, was grafted from the surface of activated carbon (AC). This material was designed to increase the flocculant's hydrophobicity and density. Different molecular weight PAM was grafted from AC with… more

    Environmental Remediation Applications of Chemically Activated Tropical Hardwood Waste

    Year: 2025, 2025
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): France, Hamant Edward, Thesis advisor (ths): Vreugdenhil, Andrew J, Degree committee member (dgc): Martic, Sanela, Degree committee member (dgc): Narine, Suresh, Degree granting institution (dgg): Trent University
    Abstract: <p>Innovative strategies to manage copious waste streams by upcycling feedstocks to valorized products which are then used in environmental remediation applications is an attractive circular economy model. This thesis explores this approach using waste wood generated from the milling of Chlorocardium rodiei (greenheart), a tropical hardwood species abundant in Guyana. We evaluate the… more

    N-Heterocyclic Carbenes: Studies in Metallation, Ligand Modification, and Property Determination

    Year: 2025, 2025
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Lim, Meilin, Thesis advisor (ths): Keske, Eric C, Degree committee member (dgc): Vreugdenhil, Andrew J, Degree committee member (dgc): Zenkina, Olena V, Degree committee member (dgc): Singer, Robert D, Degree granting institution (dgg): Trent University
    Abstract: <p>N-Heterocyclic Carbenes (NHCs) have significantly impacted organometallic chemistry as ligands in transition metal catalysis, offering strong electron-donating properties and high bond dissociation energies. However, their structural versatility is limited by the scarcity of commercial precursors and challenging modification procedures. Furthermore, we have investigated its coordination… more

    Grafting Polyacrylamide from the Surface of Activated Carbon for Flocculation Applications

    Year: 2023, 2023
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Begin, Sarah, Thesis advisor (ths): Vreugdenhil, Andrew J, Degree committee member (dgc): Zenkina, Olena, Degree committee member (dgc): Bradac, Carlo, Degree granting institution (dgg): Trent University
    Abstract: <p>The generation of polymer brushes by surface-initiated polymerization techniques has become a powerful tool for the creation of hybrid materials. Governed by the type and amount of polymer used in the modification, the chemical and physical properties of a surface can be tailored by polymer grafting. In this study, a commonly used polymer flocculant, polyacrylamide (PAM), was grafted… more
    Full Text: Grafting Polyacrylamide from the Surface of Activated Carbon for Flocculation Applications A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Master of Science in the Faculty of Arts and …

    Extraction and Characterization of Hyaluronic Acid and Collagen from Eggshell Membrane Waste: An Industrial Recycling Process

    Year: 2021, 2021
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Stabler Ogawa, Jayme Larissa, Thesis advisor (ths): Vreugdenhil, Andrew J, Degree committee member (dgc): Wortis, Rachel, Degree committee member (dgc): Rizvi, Ghaus, Degree granting institution (dgg): Trent University
    Abstract: <p>Connecting academia to industry is one important way to advance towards meeting the United Nations (UN) Sustainability Goals (SDGs).1 Sustainability can be applied to all industrial sectors with the SDGs being implemented by 2030.2 This research contributes to the SDGs by investigating a way to remediate an industrial waste stream in the egg-breaking industry. If adopted, this would… more
    Full Text: Extraction and Characterization of Hyaluronic Acid and Collagen from Eggshell Membrane Waste: An Industrial Recycling Process A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Doctor of …

    UV-Curable hybrid sol-gel materials: The development and application of a 3-methacryloxypropytrimethoxysilane-derived coating

    Year: 2021, 2021
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Scotland, Kevin, Thesis advisor (ths): Vreugdenhil, Andrew J, Degree committee member (dgc): Zenkina, Olena, Degree committee member (dgc): Parnis, Mark, Degree committee member (dgc): Zelisko, Paul, Degree committee member (dgc): Atkinson, Bill, Degree granting institution (dgg): Trent University
    Abstract: <p>This thesis describes the synthesis, application and evaluation of a UV crosslinked 3-methacryloxypropyltrimethoxysilane-derived coating formulation. This is a two-component sol-gel system with 3-methacryloxypropyltrimethoxysilane (MaPTMS) and tetraethoxysilane (TEOS). Herein we show that if we change the co-solvent required for solubilizing MaPTMS from the more common methanol and… more
    Full Text: UV-Curable hybrid sol-gel materials: The development and application of a 3methacryloxypropytrimethoxysilanederived coating A Thesis submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Doctorate of …

    Electrochemical Characterization of Giardia Intestinalis Cytochromes b5

    Year: 2016, 2016
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Yang, Zhen (Alice), Thesis advisor (ths): Rafferty, Steven P, Degree committee member (dgc): Vreugdenhil, Andrew J, Degree committee member (dgc): Saville, Barry J, Degree granting institution (dgg): Trent University
    Abstract: <p>Giardia intestinalis is a protozoan parasite that causes waterborne diarrheal disease in animals and humans. It is an unusual eukaryote as it lacks the capacity for heme biosynthesis; nonetheless it encodes heme proteins, including three cytochrome b5 isotypes (gCYTB5s) of similar size. Homology modelling of their structures predicts increased heme pocket polarity compared to mammalian… more
    Full Text: ELECTROCHEMICAL CHARACTERIZATION OF GIARDIA INTESTINALIS CYTOCHROMES b5 A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Masters of Science in the Faculty of Arts and Science TRENT …