Trent University Graduate Thesis Collection

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    Copyright for all items in the Trent University Graduate Thesis Collection is held by the author, with all rights reserved, unless otherwise noted.
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    Advancements and Challenges in Ciguatoxin Detection: Developing a High- Resolution Mass Spectrometric Method for the Identification of P-CTX-3B

    Year: 2024, 2024
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Prytulka, Natasha Grace, Thesis advisor (ths): Hintelmann, Holger, Thesis advisor (ths): Stock, Naomi, Degree committee member (dgc): Metcalfe, Chris, Degree granting institution (dgg): Trent University
    Abstract: <p>The detection of ciguatoxins (CTXs) in biological samples is challenging due to their low concentrations, the presence of various congeners, and the absence of standardized methods. This study uses high resolution mass spectrometry (HRMS) with P-CTX-3B as a reference standard. The protonated molecules ([M+H]+) were most prevalent, especially when acetonitrile/water was utilized,… more

    A collaborative ecotoxicological risk assessment of in-place pollutants in Owen Sound Bay, Lake Huron within the Saugeen Ojibway Nation Territory

    Year: 2021, 2021
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Buell, Mary Claire Claire, Thesis advisor (ths): Metcalfe, Chris, Degree committee member (dgc): Furgal, Chris, Degree committee member (dgc): Gueguen, Celine, Degree granting institution (dgg): Trent University
    Abstract: <p>Owen Sound Bay, which is located within the traditional territory of the Saugeen Ojibway Nation (SON), is contaminated as a result of historical industrial and shipping activity. Gross contamination of the sediments in the inner part of the Bay (i.e., Owen Sound Harbour) includes high concentrations of polycyclic aromatic hydrocarbons (PAHs) and other organic compounds, as well as metals… more

    Composition and Transformation of Dissolved Organic Matter in Hudson Bay, Canada

    Year: 2021, 2021
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Islam, Sohidul, Thesis advisor (ths): Gueguen, Celine, Degree committee member (dgc): Aherne, Julian, Degree committee member (dgc): Metcalfe, Chris, Degree granting institution (dgg): Trent University
    Abstract: <p>The Hudson Bay region is a sensitive environment, where anthropogenic (e.g., dams, diversions, and/or reservoirs) impacts have increased in recent decades, potentially influencing the functioning of the ecosystem. Dissolved organic matter (DOM) entering Hudson Bay comes from both terrestrial (allochthonous) and aquatic (autochthonous) sources. The chemical composition of DOM is important… more

    Assessing Measured and Perceived Risks to Drinking Water Sources: Comparative Case Studies in Small, Rural Communities

    Year: 2020, 2020
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Serville-Tertullien, Marsha Dawn Helena, Thesis advisor (ths): Metcalfe, Chris, Degree committee member (dgc): Furgal, Chris, Degree committee member (dgc): Whillans, Tom, Degree granting institution (dgg): Trent University
    Abstract: <p>Microcontaminants originating from wastewater effluent and run-off from agricultural lands may be present in the sources of drinking water for rural and Indigenous communities in mixed-use watersheds. In this study, a convergent parallel mixed-methods design was applied to assess measured and perceived risks of contamination in the sources of drinking water for two communities; the Six… more

    Tracking Mercury and Mercury Stable Isotopes Throughout the Wabigoon/English River System: A Preliminary Assessment

    Year: 2020, 2020
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): McGovarin, Stephen Adam, Thesis advisor (ths): Hintelmann, Holger, Thesis advisor (ths): Metcalfe, Chris, Degree granting institution (dgg): Trent University
    Abstract: <p>In the Wabigoon/English River system, mercury concentrations downstream from Dryden, ON, where there was a former chlor-alkali plant, remain elevated in sediments and biota. Understanding the current extent and severity of mercury contamination downstream from the former chlor-alkali plant is of great interest in furthering the clean-up of mercury within the traditional territory of… more

    Novel Aliphatic Amides from Vegetable Oils as Bio-Based Phase Change Materials

    Year: 2020, 2020
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Poo Palam, Kosheela, Thesis advisor (ths): NARINE, SURESH S, Degree committee member (dgc): Vreugdenhil, Andrew, Degree committee member (dgc): Hill, Stephen, Degree committee member (dgc): Metcalfe, Chris, Degree granting institution (dgg): Trent University
    Abstract: <p>Energy storage efficiency and sustainability require advanced technologies and novel materials. Recently, bio-based phase change materials (PCMs) have received significant attention for thermal energy storage (TES) uses. Vegetable oils are versatile renewable feedstocks that are well suited for the development of sustainable, functional PCMs. PCMs derived from vegetable oil, which… more

    Study of Aerosols for use in Water Remediation of Pharmaceutical Pollutants

    Year: 2019, 2019
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Roy, Tyler Mackenzie, Thesis advisor (ths): Ellis, David, Degree committee member (dgc): Metcalfe, Chris, Degree committee member (dgc): Parnis, Mark, Degree granting institution (dgg): Trent University
    Abstract: <p>In this thesis, aerosolization was studied as a possible means of water remediation for several environmentally relevant pharmaceutical pollutants, known for their persistence in wastewater effluent and potable water sources. Seven different pharmaceutical compounds and a well-known plasticizer were all shown to decrease considerably in concentration in aerosol that was produced and… more

    Characterization of Synthetic and Natural Se8 and Related SenSm Compounds by Gas Chromatography-Mass Spectrometry

    Year: 2019, 2019
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Farell, Jana, Thesis advisor (ths): Wallschläger, Dirk, Degree committee member (dgc): Hintelmann, Holger, Degree committee member (dgc): Metcalfe, Chris, Degree granting institution (dgg): Trent University
    Abstract: <p>Elemental selenium has been extensively quantitatively measured in sediments; however, its physical composition is largely unknown, despite it being the dominant selenium species in some reducing environments. Here, for the first time, it is shown that small, cyclic selenium compounds can account for a quantitatively-relevant fraction of the total elemental selenium present. </p>… more

    Protecting Sources of Drinking Water for the M'Chigeeng First Nation, Manioulin Island, Ontario

    Year: 2018, 2018
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Herman, Richard, Thesis advisor (ths): Metcalfe, Chris, Degree committee member (dgc): Gueguen, Celine, Degree committee member (dgc): Furgal, Chris, Degree granting institution (dgg): Trent University
    Abstract: <p>The potential impacts of domestic wastewater (DWW) on the source of drinking water for the M'Chigeeng First Nation were monitored as part of the development of a Source Water Protection plan. During a period of continuous overflow of the Gaaming Wastewater Lagoon serving the community, the chemical tracers, caffeine and sucralose were tracked in West Bay with Passive Organic… more

    Mercury and Persistent Organic Pollutants in Remote Acid Sensitive Irish Lake Catchments

    Year: 2017, 2017
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): McFarland, Victoria, Thesis advisor (ths): Aherne, Julian, Degree committee member (dgc): Metcalfe, Chris, Degree committee member (dgc): Hintelmann, Holger, Degree granting institution (dgg): Trent University
    Abstract: <p>A catchment-based study was carried out at three remote acid sensitive Irish lakes to determine concentrations of Hg and POPs and to investigate the factors governing the partitioning of these pollutants in various environmental matrices. Both Hg and POPs are an environmental concern due to their ability to travel long distances via atmospheric transport and their tendency to accumulate… more

    Effect of the neonicotinoid imidacloprid on embryogenesis and anuran survivorship in frog virus 3 infected tadpoles

    Year: 2017, 2017
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Hrynyk, Morgan Anne, Thesis advisor (ths): Metcalfe, Chris, Degree committee member (dgc): Kerr, Leslie, Degree committee member (dgc): Brunetti, Craig, Degree granting institution (dgg): Trent University
    Abstract: <p>Exposure of pre-metamorphic amphibians to neonicotinoid insecticides may be contributing to the global decline in amphibian populations. In this study, anuran embryos and tadpoles of the African clawed frog (Xenopus laevis) and the North American leopard frog (Lithobates pipiens) were used to determine the effects of embryonic exposure to neonicotinoids. In addition, Xenopus was used to… more

    Detecting anti-estrogens and anti-androgens in surface waters impacted by municipal wastewater discharges and agricultural runoff

    Year: 2017, 2017
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Corcoran, Shawna Karen Jackson, Thesis advisor (ths): Metcalfe, Chris, Degree committee member (dgc): Ellis, David, Degree committee member (dgc): Gueguen, Celine, Degree granting institution (dgg): Trent University
    Abstract: <p>This study focused on detecting 22 target anti-estrogenic and anti-androgenic compounds in surface waters influenced by both discharges of municipal wastewater and agricultural runoff in Canada and Argentina. Polar organic chemical integrative samplers (POCIS) were used to monitor the target compounds in surface waters. The removals of the target compounds in a municipal wastewater… more

    Bio-based Polymers from Epoxidized Vegetable Oils Modified by Metathesis

    Year: 2016, 2016
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Persaud, Avinaash Antonio, Thesis advisor (ths): Narine, Suresh, Degree committee member (dgc): Rafferty, Steven, Degree committee member (dgc): Metcalfe, Chris, Degree granting institution (dgg): Trent University
    Abstract: <p>The epoxides of oligomeric self-metathesized soybean oil (MSBO) and cross-metathesized palm oil (PMTAG) and canola oil (CMTAG) containing terminal double bonds were used to produce nonisocyanate polyurethanes (NIPUs) as well as anhydride, amine and thiol-cured epoxies. </p><p>The synthesized NIPUs displayed metal adhesive properties for CMTAG and MSBO with MSBO being favoured… more

    Lipid-derived Thermoplastic Poly(ester urethane)s: Effect of Structure on Physical Properties

    Year: 2016, 2016
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Shetranjiwalla, Shegufta, Thesis advisor (ths): NARINE, SURESH S, Thesis advisor (ths): Vreugdenhil, Andrew, Degree committee member (dgc): Metcalfe, Chris, Degree committee member (dgc): Dawson, Peter, Degree granting institution (dgg): Trent University
    Abstract: <p>Thermoplastic poly(ester urethane)s (TPEU)s derived from vegetable oils possess inferior physical properties compared to their entirely petroleum-based counterparts due to the structural limitations and lower reactivity of the precursor lipid-derived monomers. The present work shows that high molecular weight of TPEUs with enhanced performance can be obtained from lipid-derived monomers… more

    Nitrogen and phosphorus bioavailability in soil amended with alkaline stabilized biosolids

    Year: 2015, 2015
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Halloran, Samantha, Thesis advisor (ths): Sharifi, Mehdi, Degree committee member (dgc): Metcalfe, Chris, Degree committee member (dgc): Price, Gordon, Degree granting institution (dgg): Trent University
    Abstract: <p>Agricultural land application of biosolids recycles nutrients and organic matter to the soil, however the effect of treatment process on nutrient availability requires further research for better nutrient management. This study examined the bioavailability of nitrogen (N) and phosphorus (P) in alkaline treated biosolids (TB) when amended into three different soils. Despite a 45%… more

    Effects of Silver Nanoparticles on Lake Bacterioplankton

    Year: 2014, 2014
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Blakelock, Graham Charles, Thesis advisor (ths): Frost, Paul C, Degree committee member (dgc): Metcalfe, Chris, Degree committee member (dgc): Hickie, Brendan, Degree granting institution (dgg): Trent University
    Abstract: <p>Silver nanoparticles (AgNP) released into aquatic environments could threaten natural bacterial communities and ecosystem services they provide. We examined natural lake bacterioplankton communities' responses to different exposures (pulse vs chronic) and types (citrate and PVP) of AgNPs at realistic environmental conditions using a mesocosm study at the Experimental Lakes Area. An… more

    Fate of Silver Nanoparticles in Lake Mesocosms

    Year: 2014, 2014
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Furtado, Lindsay Mira, Thesis advisor (ths): Metcalfe, Chris, Thesis advisor (ths): Hintelmann, Holger, Degree committee member (dgc): Kirk, Jane, Degree granting institution (dgg): Trent University
    Abstract: <p>The fate of silver nanoparticles (AgNPs) in surface waters determines the ecological risk of this emerging contaminant. In this research, the fate of AgNPs in lake mesocosms was studied using both a continuous (i.e. drip) and one-time (i.e. plug) dosing regime. AgNPs were persistent in the tested lake environment as there was accumulation in the water column over time in drip mesocosms… more

    The Development and Use of Passive Samplers for Monitoring Dissolved and Nanoparticulate Silver in the Aquatic Environment

    Year: 2013, 2013
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Fischer, Jillian Gould, Thesis advisor (ths): Metcalfe, Chris, Thesis advisor (ths): Hintelmann, Holger, Degree granting institution (dgg): Trent University
    Abstract: <p>Silver nanoparticles (nAg) are the largest and fastest growing class of nanomaterials, and are a concern when released into aquatic environments even at low &mu;g L<super>-1</super. levels. Measurement at environmental levels requires extremely sensitive instrumentation, therefore this research developed two passive samplers to track the the concentration of nAg and… more