Expression of Giardia intestinalis flavoenzyme GiOR-1 and characterization of its electron transfer properties

Abstract

Giardia intestinalis possesses four isotypes of cytochrome b5 (gCYTB-I-IV) that differ from their mammalian counterparts, suggesting different functions in this protozoan parasite. Although the recently discovered Giardia flavoenzyme, GiOR-1, reduces these cytochromes, its properties have not been thoroughly studied, owing to the difficulty in its expression. Here I describe successful conditions for expression of GiOR-1 using autoinduction. GiOR-1 is obtained with flavins bound as indicated by its UV-visible spectrum. Its ability to catalyze electron transfer from donors (NADH, NADPH) to acceptors (oxygen, ferricyanide, cytochrome c, gCYTB5-III) were studied in spectrophotometric rate assays. NADPH is the preferred electron donor, while cytochromes are the preferred electron acceptors. Interestingly, the His-tag used to purify gCYTB5-III decreases its reaction rate with GiOR-1, as an untagged version has slightly faster rates. These findings establish the appropriate conditions for further studies on GiOR-1, including the identification of endogenous electron acceptors.

Author Keywords: Autoinduction, Cytochrome b5, Cytochrome P450 oxidoreductase, Giardia intestinalis, GiOR-1, Polyhistidine tag

    Item Description
    Type
    Contributors
    Creator (cre): Villeneuve, Tiffany C.
    Thesis advisor (ths): Rafferty, Steven
    Degree committee member (dgc): Huber, Robert
    Degree committee member (dgc): Brunetti, Craig
    Degree granting institution (dgg): Trent University
    Date Issued
    2021
    Date (Unspecified)
    2021
    Place Published
    Peterborough, ON
    Language
    Extent
    71 pages
    Rights
    Copyright is held by the author, with all rights reserved, unless otherwise noted.
    Local Identifier
    TC-OPET-10928
    Publisher
    Trent University
    Degree
    Master of Science (M.Sc.): Environmental and Life Sciences