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The objective of this dissertation is to measure the influence of the contemporary influx of women's involvement in the horror genre in three dimensional capacities: female representation in horror films, female representation as active, participatory spectators and female representation in the industrial production of horror. Through the combined approach of theoretical and empirical analysis, this dissertation examines the social conditions that facilitated women's infiltration of the horror genre. Beginning with psychoanalytic theories of spectatorship, it is demonstrated that female filmmakers have challenged horror's traditional images of victimized women through the development new forms of feminine representation in contemporary horror films. Using data collected from a sample of 52 self-identified female horror fans, it is revealed that the purported invisibility of female horror spectators is a consequence of their alternative modes of consumption. Through interviews conducted with four female producers and an examination of their cultural productions, I illustrate that women have reconstituted the horror genre as a space for inclusivity, political activism and feminist empowerment. Cohesively, these findings reveal the contemporary feminist reclamation of horror to be a form of resistance intended to challenge the patriarchal structures that facilitated women's historical exclusion from the horror genre.

Author Keywords: Abjection, Feminism, Film, Gender, Horror, Psychoanalysis

This thesis describes the synthesis, application and evaluation of a UV crosslinked 3-methacryloxypropyltrimethoxysilane-derived coating formulation. This is a two-component sol-gel system with 3-methacryloxypropyltrimethoxysilane (MaPTMS) and tetraethoxysilane (TEOS). Herein we show that if we change the co-solvent required for solubilizing MaPTMS from the more common methanol and ethanol to isopropanol we change the rate of hydrolysis from days or weeks to minutes. With the assistance of 2D 29Si-NMR we demonstrate that the system undergoes extensive condensation in twenty minutes. Using standard UV irradiation, the material can be extensively UV crosslinked with 70% of the methacryloxy functionality being consumed in 5 minutes upon irradiation in the presence of a photo-initiator. When this material is used to coat low carbon steel and immersed in an accelerated corrosion solution (dilute Harrison's solution); this material affords low carbon steel 25 hours of protection when crosslinked and 17 hours of protection when uncrosslinked.

The material was then used to encapsulate polyaniline (PANI), an intrinsic conductive polymer used in the corrosion protection of metal substrates. PANI has been encapsulated previously in sol-gel material, but due to the pH dependence of the solubility of PANI, it can not be encapsulated in more commonly chemically crosslinked sol-gel. As our system is UV crosslinked rather than chemically crosslinked, we were able to successfully demonstrate the inclusion of PANI into our coating system.

Finally, this thesis includes a thorough computational investigation into the structure and band gap of PANI. Through the analysis of the band gap it was shown that the structure of the polymer commonly displayed in literature is not the correct structure of the polymer. Our results suggest that when PANI is made electrochemically, the oligomer contains two quinoid units next to one another instead of the more usually represented regularly alternating benzoid and quinoid units. The results also suggest that when PANI is made using the oxidant ammonium persulfate, the polymer most likely contains a Michael adduct structure somewhere in the polymer chain which dominates PANI's electronic properties.

Author Keywords: 3-Methacryloxypropyltrimethoxysilane, Computational Chemistry , Corrosion , Polyaniline, Tetraethoxysilane

This thesis established the variability of Late Paleoindian bifacial stone tool assemblage from the Kruger 2 site. Kruger 2 is a basecamp occupied during the Pleistocene-Holocene transition in the Eastern Townships, Southern Quebec. The goal of this project is to quantify the variability observed in bifacial tools and to explain it. Geometrics Morphometrics and traditional attributed-base lithic analysis are used conjointly for this purpose. Geometrics Morphometrics are a set of methods that are used to distinguish groups based on their shape and to understand the differences between those groups. It is used to test the validity of the morpho-types used to classify bifacial tools found on Kruger 2 (bifaces, drills, Ste-Anne-Varney points, Agate Basin points, and other projectile points). In terms of explanation, the organization of technology postulates (sensu Nelson 1991) lies at the core of the research. The analysis involved defining the factors of biface shape variation and evaluating whether shape variation is caused primarily by raw material, function, tool life histories, or other design constraints. It was determined that all three of these factors contribute to shape differences. The data suggest that the primary factors are raw material availability and tool life histories – two factors intimately intertwined. In other words, it is the organization of technology that seems to be the driving explanatory force that accounts for shape variability.

Author Keywords: Eastern Towhships, Geometrics Morphometrics, Late Paleoindian, Organization of technology, Pleistocene-Holocene Transition, Stonetool variability

This thesis examines low-ranking British soldiers' memoirs in the nineteenth century to determine the extent to which they identified with Christianity and how their expressions of faith differed from each other. Using twelve narratives published between 1811–1863, it finds that all of these soldiers identified themselves with Protestant Christianity and, more importantly, considered irreligion an evil which could not be justified by any decent British citizen. Furthermore, it argues that soldiers' identity construction was largely determined by the degree of depth of their religious understanding. It uses the work of William Wilberforce to contextualize these soldiers' expressions of faith and demonstrates how military writing can be more fully understood as representing a spectrum between nominal Christianity and real or true Christianity. This project strives to demonstrate that the religiosity of eighteenth- and nineteenth-century Britain has a significant impact upon our understanding of their time.

Author Keywords: Britain, Christianity, memoirs, Military, soldiers, William Wilberforce

This thesis explores the history of the Indigenous child welfare system in Manitoba and the effects of the Millennium Scoop on children in care. My research question is: what was the experience of children in care in Manitoba from 1990 to 2015? A related question is: how do survivors find healing? The thesis begins with a discussion of the history of acts, policies, and practices that began with the Indigenous child welfare system during the running of Residential schools. Then the acts, reviews, and policies that have shaped the child welfare system in Manitoba are discussed more thoroughly. The focus of the thesis is on the stories of Phoenix Sinclair, Tina Fontaine, and Natasha Reimer. I share their stories and provide an analysis of how the child welfare system has affected their lives. The negative effects of being a child in care are numerous. Being a child in care leaves behind grief, loss of identity, and loss of security. The systemic issues of the child welfare system include inadequate funding, overloaded case workers, staff burnout, and a lack of transparency. These overarching failures translate into the failure of children in care: details are overlooked, wrong decisions are made, and children are left to fend for themselves. Or they fall into the cracks and do not receive adequate care. This then translates into the deaths of children in care, or they are left to navigate life on their own and forced to create their circle of supports. Despite all the complications and negative impacts, some children can succeed while in care. Natasha's story is a perfect example of such resilience.

Author Keywords: child welfare, indigenous studies, millennium scoop, sixties scoop

Line transect sampling and photographic-identification (photo-ID) are common survey techniques for estimating the abundance and distribution of cetaceans. Combining these approaches in the field ('combined LTPI' surveys) and using data from both components has the potential for generating comprehensive ecological knowledge that can be far more valuable than when these techniques and their data are used independently. In this thesis, I evaluated the results and conclusions from these two methods, used singly and in tandem, by investigating the population dynamics of two humpback dolphin (Sousa chinensis spp.) populations: the large and widely distributed Chinese white dolphin (S. c. chinensis) of the Pearl River estuary (PRE), and the small and geographically isolated subspecies of Taiwanese white dolphin (S. c. taiwanensis) in the eastern Taiwan Strait. Data from combined LTPI surveys in Hong Kong waters, at the eastern edge of the PRE, revealed a shift in space use with individuals spending less time in these waters than at the start of surveys. Data from combined LTPI surveys in Taiwan provided further support for a subspecies restricted to the central western waters, and identified a commonly used area at the northern part of their limited range. These two case studies demonstrated an overall efficacy of combined LTPI surveys in ecological studies of cetaceans. However, a multi-criteria analysis revealed that combined LTPI surveys with a line transect focus (e.g., Hong Kong) performed better than a LTPI survey with a photo-ID focus (e.g., Taiwan) when considering ecological aspects of the study populations, labour and data requirements, and ecological output. Even so, the photo-ID focus of Taiwan's monitoring program led to better assessments of individual space use patterns, likely helped by the Taiwanese white dolphin population's smaller size and intensive photographic effort. In both cases, the ecological output of combined LTPI surveys could be improved by expanding the study area or extending the field season or frequency of surveys. Overall, I showed that by following a set of general guidelines, different iterations of the combined LTPI approach (i.e., photo-ID focus or LT focus) can serve as powerful tools for uncovering multi-dimensional ecological information on cetaceans.

Author Keywords: abundance, cetacean, distribution, line transect sampling, multi-criteria analysis, Photo-ID

Sudbury, Ontario is an epicenter of research on industrially degraded landscapes. Regreening efforts over the past 40 years have changed the landscape, leading to an increase in forest cover in the "barrens", that once covered more than 100,000 ha. This study characterized changes in plant and insect composition using a space for time approach in the pine plantations. A total of 25 treated sites were sampled and soil characteristics, understory plants and insect communities were assessed. All sites were contaminated with copper and nickel, but the metals had little influence on biodiversity. Vegetation diversity metrics were more strongly correlated with the pH of the organic soil horizons, while the insect community shows little response to site characteristics, and rather vegetation cover. Plant composition changes are similar to those in pine stands undergoing natural recovery and as liming effects fade there may be a decline in insect community richness.

Author Keywords: Biodiversity, Heavy Metals, Mining, Remediation

In endotherms, physiological functioning is optimized within a narrow range of tissue temperatures, meaning that the capacity to dissipate body heat is an important parameter for thermoregulation and organismal performance. Yet, experimental research has found mixed support for the importance of heat dissipation capacity as a constraint on reproductive performance. To investigate the effects of heat dissipation capacity on organismal performance, I experimentally manipulated heat dissipation capacity in free-living tree swallows, Tachycineta bicolor, by trimming feathers overlying the brood patch, and monitored parental provisioning performance, body temperature, and offspring growth. I found that individuals with an enhanced capacity to dissipate body heat (i.e., trimmed treatment) provisioned their offspring more frequently, and reared larger offspring that fledged more consistently. Although control birds typically reduced their nestling provisioning rate at the highest ambient temperatures to avoid overheating, at times they became hyperthermic. Additionally, I examined inter-individual variation in body temperature within each treatment, and discovered that body temperature is variable among all individuals. This variability is also consistent over time (i.e., is repeatable), irrespective of treatment. Further, I found that individuals consistently differed in how they adjusted their body temperature across ambient temperature, demonstrating that body temperature is a flexible and repeatable physiological trait. Finally, I used a bacterial endotoxin (lipopolysaccharide) to examine the regulation of body temperature of captive zebra finches (Taeniopygia guttata) during an immune challenge. Exposure to lipopolysaccharide induces sickness behaviours, and results in a fever, hypothermia, or a combination of the two, depending on species and dosage. I asked what the relative role of different regions of the body (bill, eye region, and leg) is in heat dissipation/retention during the sickness-induced body temperature response. I found that immune-challenged individuals modulated their subcutaneous temperature primarily through alterations in peripheral blood flow, particularly in the legs and feet, detectable as a drop in surface temperature. These results demonstrate that the importance of regional differences in regulating body temperature in different contexts. Taken together, my thesis demonstrates that heat dissipation capacity can affect performance and reproductive success in birds.

Author Keywords: body temperature, heat dissipation, tree swallow, zebra finch

The contemporary denigration of poultry combined with the intensification of industrialized animal agriculture has deepened divides between humans and poultry, creating a disconnect that holds implications for both parties and the sustainability of North American food systems. This study explores how people with poultry keeping experience perceive these animals, how their views are influenced and how these narratives may intersect with themes of sustainability. Surveys and interviews aimed at small flock keepers and commercial farmers within an area of Central Ontario revealed that poultry sentience was widely recognized among participants. Overall, this study's findings disrupt commonly held notions that poultry are one-dimensional beings and highlight the mutual benefits that can come when the distance is lessened between humans and poultry. This research contends that reimagining human-poultry relationships could improve our ability to consider and challenge dominant systems that perpetuates unsustainable food production and negatively affects both animal and human life.

Author Keywords: history poultry keeping, human-animal studies, human-poultry relationships, keeper attitudes, poultry sentience, sustainable food systems

Connecting academia to industry is one important way to advance towards meeting the United Nations (UN) Sustainability Goals (SDGs).1 Sustainability can be applied to all industrial sectors with the SDGs being implemented by 2030.2 This research contributes to the SDGs by investigating a way to remediate an industrial waste stream in the egg-breaking industry. If adopted, this would reduce the amount of eggshell membrane (ESM) waste placed in landfill where it does not decompose properly. The work described in this thesis specifically targets extraction of collagen and hyaluronic acid (HA), two components of the ESM that are of commercial value in the cosmetic, pharmaceutical, and biomedical industries3,4 . Deliverables from this research include economically viable extraction methods, developed based on green chemistry approaches, that can be transferred from lab bench to industrial scale. The extraction development process was guided by the 12 Principles of Green Chemistry5,6,7 and the 12 Principles of Green Engineering.8 HA was most successfully extracted using a sodium acetate solution on ground ESM. Filtrate was collected, exhaustively dialyzed and lyophilized. High molecular weight HA was recovered. Fourier transform infrared attenuated total reflectance (FTIR-ATR) spectroscopy and proton nuclear magnetic resonance (NMR) spectroscopy compared extracted material to reference HA identifying successful extraction. Collagen was extracted using acetic acid or pepsin enzyme digestion. Hydrophilic interaction liquid chromatography (HILIC) coupled with mass spectrometry (MS) compared amino acid composition of extracted materials to reference collagen material. FTIR-ATR spectra also supported successful extraction of collagen. This work identifies that HA and collagen can be conveniently extracted from ESM using an economical approach that can be implemented into egg-breaking facilities. This work highlights the benefits of connecting academia to industry to advance green chemical approaches while implementing sustainable practices into existing industry.

Author Keywords: collagen, eggshell membrane waste, extraction, green chemistry, hyaluronic acid, sustainability