eng

This dissertation explored how rural communities enhance the capacity of youth to both navigate and negotiate healthy identities and well-being in the context of social ecological resilience. Resilience refers to the capacity for individuals to have good outcomes in spite of exposure to significant adversity. Rural communities are often identified as places of deficit both in scholarly literature and in general social discourse which can constitute adversity. Given the importance of place as a social determinant of health, rural communities can have a notable impact on the positive development of adolescent identity and well-being of the youth that reside within them.

Drawing on the concept of social ecological resilience which draws attention to the importance of environments and relationships to support development, this project engaged with high school aged adolescents (14 to 18 years old) from Haliburton County in Central Ontario. Leveraging mixed model methods, the project featured both quantitative and qualitative approaches. There were 63 participants (33 male, 28 female and 2 non-binary) for the quantitative phase of the research which made use of the Child and Youth Resilience Measure survey instrument. The second phase of the research was qualitative and featured 14 participants who engaged in six focus groups. The focus groups provided context specific awareness of place-based factors which participants found supportive in their development.

The results indicated that while the overall resilience scores for the community were lower than the national average (t(62) = 3.20, p <0.01), some study participants found the community to be resilience bolstering. Specifically, participants recognized the importance of supportive people, an awareness of an enriched sense of community, and a powerful sense of the value of nature and the outdoors to be the most significant aspects for the development of their resilience.

The results indicate that rural youth are not naïve to the complexity of their circumstances but are able to use their rural contexts to develop the capacity to negotiate and navigate towards healthy identities and well-being.

Author Keywords: Adolescent, Place-based, Resilience, Rural, Social Ecological, Youth

The purpose of the current study was to explore the relationships between sexting, perceptions of sexual consent, and nonconsensual sexual experiences (NSEs). Participants consisted of 100 community members and 851 undergraduate students enrolled at Trent University. It was found that males were more likely than females to interpret ambiguous sexual scenarios as consensual, but consent perceptions were not influenced by sexting. When examining past personal experiences, males interpreted received sext messages as an indicator of consent significantly more than females, while females were more likely to interpret received messages as more harassing. NSEs were significantly related to sexting behaviours: those who engage in sexting were more likely to also have experienced a NSE, and 20.5% of participants in the current study reported having experienced a NSE with a consensual sexting partner. The current study has important implications for the future of sexting research, practice, and policy.

Author Keywords: nonconsensual sexual experiences, sexting, sexual assault, sexual consent, sexual harassment

This thesis is about the negative impacts on queer identities caused by the lack of diversity related to sexual orientation within Ontario Ministry of Education curriculum documents, both at the elementary and secondary level. Curriculum documents as well as policy documents are analysed and compared in order to address the lack of diverse sexual orientation representation within Ontario's education system. The study is guided by the question: "who benefits from the current representations of sexual orientation in the curriculum?" This conceptual study advances autobiographical methodology and the concept of Currere in relation to queer theory that allows researchers to analyse their educational experiences throughout the course of their lives and then become agents of social change. The results of my personal curriculum analysis have shown that curriculum documents lack diverse sexual orientation representation and that this has negative impacts how LGBQQ people identify and on the course of their lives.

Author Keywords: Curriculum, Homophobia, LGBQQ, Ontario Curriculum, Ontario Education, Sexual Orientation

Sexting was explored in relation to cohabitation status, general and sexual communication, as well as the anxious and avoidant dimensions of attachment. The present study was focused the distinction between lifetime and recent sexting, in an attempt to more accurately assess the relationships between the examined factors and sexting behaviours. Individuals in long-distance relationships were more likely to report recently sexting and engaged more frequently than those in cohabitating relationships, but did not differ in their levels of sexual satisfaction. Recent sexters reported higher levels of sexual communication compared to lifetime sexters, and sexual communication was positively, though weakly, correlated with sexting frequency. The present study was unable to support a predictive relationship between recent sexting and levels of attachment anxiety or avoidance. These results highlight the importance of exploring the context in which sexting occurs, as well as distinguishing between lifetime and recent sexters in future sexting research.

Author Keywords: Attachment, Long Distance Relationship, Recent Sexting, Satisfaction, Sexting, Sexual Communication

Mixtures of metals occur in surface waters, toxicity of which has drawn world-wide attention due to their crucial role in both ecotoxicology and regulations. The present research was undertaken to study the acute toxicity of binary mixtures of Ni, Cu, Zn, and Cd to the freshwater organism, Daphnia magna. The experimental approach included single and binary metal toxicity tests based on the 48h acute toxicity bioassay of Environment Canada. The acute toxicity of single metals followed the order of Cd > Cu > Zn > Ni. Based on the calculated 48h EC50 value of single metals, a toxic unit (TU) approach was used to combine two metals in a binary mixture, in which 1TU was equal to the 48h EC50 value of a metal in single exposure. The toxicity of binary metal mixtures to D. magna followed the order of Cu-Cd > Cu-Zn > Zn-Cd > Cu-Ni > Zn-Ni > Cd-Ni, which demonstrated three types of toxicity (i.e., less than additive, additive, and greater additive). Predictions from additivity models (including concentration addition (CA) and independent action (IA) models), a generalized linear model (GLM), and a biotic-ligand-like model (BLM-like) were compared to the bioassay results. The CA and the RA models also predicted three types of toxicity of the binary metal mixtures (i.e., less than additive, additive, and greater than additive). However, the CA model mostly overestimated the toxicity of binary mixtures. Predictions from the GLM supported the inclusion of the interaction between two metals in a mixture to predict the toxicity of binary metal mixtures. The binary metal toxicity was also predicted using a BLM-like model based on the calculated concentrations of free ionic forms of the metals, affinity constants, and toxic potency of each metal. In this model, it was hypothesized that the toxicity of metal mixture is the result of competition of metals with Ca2+ at biotic ligands, which can lead to whole-body deficiency of Ca2+ in D. magna. The BLM-like model provided the toxic potency of single metals with the following order, Cu > Cd > Zn > Ni. Although the prediction of the BLM-like model was not in good agreement with the observed toxicity of binary metal mixtures, an overestimation of risk of mixture toxicity was obtained using this model, which could be promising for use in environmental risk assessment.

Author Keywords: biotic ligand model, concentration addition, Daphnia magna, independent action, metal toxicity, modeling

This thesis investigates the similarities and differences between the tropical epicenters of South and Southeast Asia during the Charter State era, 800- 1400 CE. This study can inform scholars about the relationship between "people and place" by examining the ground plans, activities, and people associated with each epicenter. By using the comparative approach and entanglement theory, this study will examine the ancient states of Central and East Java, Dai Viet in North Vietnam, the Cham in Central Vietnam, the Chola of South India, and the Sinhalese of Sri Lanka. The ancient Maya of tropical Belize will be used as a cross-cultural comparator, which would not have had any contact with the other charter states. An extensive literature review and on-site visitations were necessary to provide the background and date to accomplish these goals. The results indicate striking similarities between tropical epicenters across the Charter States that developed out of the entanglements between humans and things. This thesis will help to further our understanding of tropical urbanism and the nature of epicenters in tropical environments.

Author Keywords: Anuradhapura, Caracol, Entanglement, Thang Long, Thanjavur, Urbanism

The goal of this thesis is to explore the role that civic (i.e. state-sponsored)

feasting and drinking played in early polis (pl. poleis), or city-state formation on Crete in

the Early Iron Age to Archaic transition, ca. 700-500 BCE. Using the two recently

excavated civic feasting structures at the site of Azoria as a model for both "inclusive"

and "exclusive" forms of civic feasting, this project compares and contrasts the role that it

played at a number of other sites in central and east Crete. In order to categorize the

structures as either inclusive or exclusive, all forms of published evidence were examined

including the buildings' architecture and the socially valued goods and ceramics found

within the structures. Ultimately, this project demonstrates that in the 8th century BCE,

inclusive feasting rituals and association with the past were used as means of creating and

maintaining a strong group identity, which paved the way for the use of more exclusive

practices in the 7th century BCE, where sub-group identities and alliances were formed

amongst members of the larger group. However, at the sites where there was evidence for

multiple civic feasting venues it appears that by the 7th century BCE, the interplay of both

inclusive and exclusive forms of feasting was crucial to the process of identity formation

for the citizens of these proto-poleis.

Author Keywords: Archaic Crete, Commensality, Feasting, Identity Formation, Polis formation

Distributing contextual fear episodes makes the memory become HPC-independent, meaning increasingly reliant on non-HPC memory structures. It is unclear, however, whether distribution of the conditioning episodes alone is sufficient or whether a combination of distribution and high conditioning saliency is necessary to make the memory become HPC-independent. To resolve this issue, rats were trained using a distributed contextual fear conditioning protocol in which foot-shocks were manipulated to create a low (0.4mA), intermediate (0.7 mA) and high (1.0 mA) saliency condition. This thesis also aimed to determine brain structures supporting the HPC-independent memory by assessing retention-induced c-fos expression in the basolateral- amygdala, perirhinal and anterior cingulate cortices. The results suggest that HPC lesion rats in the high saliency condition displayed similar level of freezing as control rats, indicating "strongly salient" and distributed episodes creates a HPC independent memory. c-fos expression suggests together, an increased context representation in the perirhinal and anterior cingulate cortices and a strengthened fear representation in the basolateral-amygdala supports the HPC-independent memory.

Author Keywords: context fear memory, distributed reinstatements, hippocampus, IEG, rat, saliency

Supercritical water (SCW) exhibits unique properties that differentiates it from its low temperature behaviour. Hydrogen bonding is dramatically reduced, there is no phase boundary between liquid and gaseous states, heat capacity increases, and there is a drastic reduction of the dielectric constant. Efforts are underway for researchers to harness these properties in the applications of power generation and hazardous waste destruction. However, the extreme environment created by the high temperatures, pressures and oxidizing capabilities pose unique challenges in terms of corrosion not present in subcritical water systems. Molecular Dynamics (MD) simulations have been used to obtain mass transport, hydration numbers and the influence on water structure of molecular oxygen, chloride, ammonia and iron (II) cations in corrosion crevices in an iron (II) hydroxide passivation layer. Solvation regimes marking the transitions of solvation based versus charge meditated processes were explored by locating the percolation thresholds of both physically and hydrogen bonded water clusters. A SCW flow through reactor was used to study hydrogen evolution rates over metal oxide surfaces, metal release rates and the kinetics for the oxidation of hydrogen gas by oxygen in SCW. Insights into corrosion phenomena are provided from the MD results as well as the experimental determination of flow reactor water and hydrogen chemistry.

Author Keywords: Flow Studies, Molecular Dynamics, Supercritical Water

This thesis elucidates the role of play and games—the ludic—in Julio Cortázar's novel Hopscotch (1966; translation of Rayuela, 1963) through a range of resonant theories. Literary gameplay dominates the formal, linguistic, affective, reflexive, and thematic dimensions of Hopscotch, which are analyzed through concepts borrowed from play theorist Roger Caillois, among others, and literary theorists including Mikhail Bakhtin and Wolfgang Iser, whose ludic theories of fiction begin to map the field of ludic fiction. The analysis positions Hopscotch as an exemplar of the ludic counter-tradition within the novel, a perennial tendency from Don Quixote to postmodernism and beyond. Hopscotch, like other ludic fictions, enacts a complex convergence of the ludic and the lucid. It provokes active reading over passive consumption, diminishes the hegemonic function of serious mimesis to elevate other forms of gameplay, notably chance, competition, vertigo, and enigma, to dominant positions, and ultimately demonstrates a profound affinity between play and critical consciousness.

Author Keywords: Bakhtin, Cortazar, Iser, Ludic, Novel, Play