Trent University Graduate Thesis Collection

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    Copyright for all items in the Trent University Graduate Thesis Collection is held by the author, with all rights reserved, unless otherwise noted.
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    Effect of t2g Orbitals on Domain Walls in Electron-Doped Perovskite Ferroelectrics

    Year: 2023, 2023
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Cornell, Brennan, Thesis advisor (ths): Atkinson, William, Degree committee member (dgc): Bradac, Carlo, Degree committee member (dgc): de Haan, Hendrick, Degree committee member (dgc): Rubel, Oleg, Degree granting institution (dgg): Trent University
    Abstract: <p>In electron-doped ferroelectrics, the free electrons can become concentrated along the domain walls which act like a conducting surface. We consider the impact of free electrons occupying the t2g orbitals on the domain walls of an electron-doped perovskite ferroelectric. We build an analytical model based on Landau-Ginzburg-Devonshire theory, and a trio of tight-binding Hamiltonians for… more

    Evaluation of Spectral Retrieval Methods for Hyperspectral Coherent Anti-Stokes Raman Scattering Microscopy

    Year: 2023, 2023
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Shafe-Purcell, John, Thesis advisor (ths): Slepkov, Aaron D, Degree granting institution (dgg): Trent University
    Abstract: <p>Coherent anti-Stokes Raman scattering (CARS) microscopy is a label-free chemical imaging modality that uses CARS as a contrast mechanism to spatially resolve materials based on their molecular vibrational spectra. Due to the presence of a non resonant background that obfuscates the chemical information contained in CARS spectra, CARS images suffer from poor contrast and cannot be readily… more

    Extraction and Characterization of Hyaluronic Acid and Collagen from Eggshell Membrane Waste: An Industrial Recycling Process

    Year: 2021, 2021
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Stabler Ogawa, Jayme Larissa, Thesis advisor (ths): Vreugdenhil, Andrew J, Degree committee member (dgc): Wortis, Rachel, Degree committee member (dgc): Rizvi, Ghaus, Degree granting institution (dgg): Trent University
    Abstract: <p>Connecting academia to industry is one important way to advance towards meeting the United Nations (UN) Sustainability Goals (SDGs).1 Sustainability can be applied to all industrial sectors with the SDGs being implemented by 2030.2 This research contributes to the SDGs by investigating a way to remediate an industrial waste stream in the egg-breaking industry. If adopted, this would… more
    Full Text: Extraction and Characterization of Hyaluronic Acid and Collagen from Eggshell Membrane Waste: An Industrial Recycling Process A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Doctor of …

    UV-Curable hybrid sol-gel materials: The development and application of a 3-methacryloxypropytrimethoxysilane-derived coating

    Year: 2021, 2021
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Scotland, Kevin, Thesis advisor (ths): Vreugdenhil, Andrew J, Degree committee member (dgc): Zenkina, Olena, Degree committee member (dgc): Parnis, Mark, Degree committee member (dgc): Zelisko, Paul, Degree committee member (dgc): Atkinson, Bill, Degree granting institution (dgg): Trent University
    Abstract: <p>This thesis describes the synthesis, application and evaluation of a UV crosslinked 3-methacryloxypropyltrimethoxysilane-derived coating formulation. This is a two-component sol-gel system with 3-methacryloxypropyltrimethoxysilane (MaPTMS) and tetraethoxysilane (TEOS). Herein we show that if we change the co-solvent required for solubilizing MaPTMS from the more common methanol and… more
    Full Text: UV-Curable hybrid sol-gel materials: The development and application of a 3methacryloxypropytrimethoxysilanederived coating A Thesis submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Doctorate of …

    Frequency-time and polarization considerations in spectral-focusing-based CARS microscopy

    Year: 2021, 2021
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Cole, Ryan, Thesis advisor (ths): Slepkov, Aaron D, Degree committee member (dgc): Atkinson, Bill, Degree committee member (dgc): Vreugdenhil, Andrew, Degree committee member (dgc): Tamblyn, Isaac, Degree granting institution (dgg): Trent University
    Abstract: <p>Spectral-focusing-based coherent anti-Stokes Raman scattering (SF-CARS) microscopy is a powerful imaging technique that involves temporally and spectrally stretching ultrashort laser pulses and controlling their frequency-time characteristics. However, a broader and more detailed understanding of the frequency-time characteristics of the laser pulses and signals involved, how they are… more
    Full Text: FREQUENCY-TIME AND POLARIZATION CONSIDERATIONS IN SPECTRAL-FOCUSING-BASED CARS MICROSCOPY A THESIS SUBMITTED TO THE COMMITTEE ON GRADUATE STUDIES IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY IN THE FACULTY OF ARTS AND …

    The Adoption of a Finite Element Model of Material Deformation Relevant to Studying Corneal Biomechanics

    Year: 2020, 2020
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Song, Yuchen, Thesis advisor (ths): Shiell, Rayf, Degree committee member (dgc): Atkinson, Bill, Degree committee member (dgc): de Haan, Hendrick, Degree granting institution (dgg): Trent University
    Abstract: <p>The human cornea is required to exhibit specific material properties to maintain its regular shape under typical intraocular pressures which then allow for its correct optical functionality. In this thesis, the basis of continuum solid mechanics and the finite element method are introduced. We use finite element modelling to simulate the extension of an effective-1d, linear-elastic bar,… more
    Full Text: The Adoption of a Finite Element Model of Material Deformation Relevant to Studying Corneal Biomechanics A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Master of Science in the Faculty …

    Supercritical Water Chemistry: Molecular Dynamics Simulations and Flow Reactor Studies

    Year: 2019, 2019
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Kallikragas, Dimitrios Theofanis, Thesis advisor (ths): Svishchev, Igor M, Degree committee member (dgc): Atkinson, Bill, Degree committee member (dgc): Kisch, Joey, Degree committee member (dgc): Chkrebtii, Anatoli, Degree granting institution (dgg): Trent University
    Abstract: <p>Supercritical water (SCW) exhibits unique properties that differentiates it from its low temperature behaviour. Hydrogen bonding is dramatically reduced, there is no phase boundary between liquid and gaseous states, heat capacity increases, and there is a drastic reduction of the dielectric constant. Efforts are underway for researchers to harness these properties in the applications of… more
    Full Text: Supercritical Water Chemistry: Molecular Dynamics Simulations and Flow Reactor Studies A Thesis Submitted to the Committee of Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy in the Faculty of Arts and …

    Phosphoric Acid Chemically Activated Waste Wood: Production, Modification and Selenium Adsorption

    Year: 2019, 2019
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Strong, Oliver Luke, Thesis advisor (ths): Vreugdenhil, Andrew, Degree committee member (dgc): Easton, Brad, Degree committee member (dgc): Slepkov, Aaron, Degree granting institution (dgg): Trent University
    Abstract: <p>Activated Carbon (AC) is commonly produced by gasification, but there has been increasing interest in chemical activation due to its lower activation temperatures and higher yields. Phosphoric acid, in particular, succeeds in both these areas. Phosphoric acid activated carbon (PAC) can be environmentally sustainable, and economically favourable, when the phosphoric acid used in the… more
    Full Text: Phosphoric Acid Chemically Activated Waste Wood: Production, Modification and Selenite and Selenate Adsorption A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements For the Degree of Master of Science in the …

    The Role of Dielectric Screening in SrTiO3-Based Interfaces

    Year: 2019, 2019
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Raslan, Amany Khalil, Thesis advisor (ths): Atkinson, Bill, Degree committee member (dgc): Wortis, Rachel, Degree committee member (dgc): Gaspari, Franco, Degree granting institution (dgg): Trent University
    Abstract: <p>We build a theoretical model for exploring the electronic properties of the two-dimensional (2D) electron gas that forms at the interface between insulating SrTiO3 (STO) and a number of perovskite materials including LaTiO3, LaAlO3, and GdTiO3. The model treats conduction electrons within a tight-binding approximation, and the dielectric polarization via a Landau-Devonshire free energy… more
    Full Text: THE ROLE OF DIELECTRIC SCREENING IN SrTiO3-BASED INTERFACES A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy in the Faculty of Arts and Science Trent University …

    Advanced broadband CARS microscopy based on a supercontinuum-generating photonic crystal fiber

    Year: 2019, 2019
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Porquez, Jeremy, Thesis advisor (ths): Slepkov, Aaron D, Degree committee member (dgc): Wortis, Rachel, Degree committee member (dgc): Gaspari, Franco, Degree committee member (dgc): Côté, Daniel, Degree granting institution (dgg): Trent University
    Abstract: <p>I have developed and improved a coherent anti-Stokes Raman scattering (CARS) microscope based on the spectral focusing (SF) technique. The CARS microscope uses an 800 nm oscillator and a photonic crystal fibre module to generate the supercontinuum Stokes. The photonic crystal fibre was originally designed to generate light beyond 945 nm which is useful for CARS microscopy in the CH/OH… more
    Full Text: ADVANCED BROADBAND CARS MICROSCOPY BASED ON A SUPERCONTINUUM-GENERATING PHOTONIC CRYSTAL FIBER A THESIS SUBMITTED TO THE COMMITTEE ON GRADUATE STUDIES IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY IN THE FACULTY OF ARTS …

    Modelling the Lanthanum Aluminate-Strontium Titanate Interface with a Modified Transverse Ising Model

    Year: 2019, 2019
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Chapman, Kelsey Sarah, Thesis advisor (ths): Atkinson, William A, Degree committee member (dgc): Wortis, Rachel, Degree committee member (dgc): de Haan, Hendrick, Degree granting institution (dgg): Trent University
    Abstract: <p>In 2004 it was discovered that a two-dimensional electron gas (2DEG) forms at the interface between lanthanum aluminate (LAO) and strontium titanate (STO). This 2DEG exhibits a variety of electronic and magnetic phenomena, motivating intense research into its applicability to electronic devices. Over the years several models have been developed in theoretical exploration of this system.… more
    Full Text: Modelling the Lanthanum Aluminate-Strontium Titanate Interface with a Modified Transverse Ising Model A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Master of Science in the Faculty of …

    A Cluster Approach Applied to the One-Dimensional Anderson-Hubbard Model

    Year: 2019, 2019
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Allum, Donovan James McMurrich, Thesis advisor (ths): Wortis, Rachel, Degree committee member (dgc): Atkinson, Bill A, Degree committee member (dgc): de Hann, Hendrick, Degree granting institution (dgg): Trent University
    Abstract: <p>S. Johri and R. Bhatt developed a real-space renormalization group approach aimed at extracting the localized single-particle eigenstates of the Anderson model from a large system by identifying clusters of resonant site potentials. E. Campbell generalized this real-space renormalization group approach using standard perturbation theory. Both approaches were intended to approximate the… more
    Full Text: A CLUSTER APPROACH APPLIED TO THE ONE-DIMENSIONAL ANDERSON-HUBBARD MODEL A Thesis submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Master of Science in the Faculty of Arts and Science Trent …

    Real-space renormalization group approach to the Anderson model

    Year: 2017, 2017
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Campbell, Eamonn Alexander, Thesis advisor (ths): Wortis, Rachel, Degree committee member (dgc): Tamblyn, Isaac, Degree committee member (dgc): Atkinson, Bill A, Degree granting institution (dgg): Trent University
    Abstract: <p>Many of the most interesting electronic behaviours currently being studied are associated with strong correlations. In addition, many of these materials are disordered either intrinsically or due to doping. Solving interacting systems exactly is extremely computationally expensive, and approximate techniques developed for strongly correlated systems are not easily adapted to include… more
    Full Text: Real-space renormalization group approach to the Anderson model A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Master of Science in the Faculty of Arts and Science Trent University …

    A silicon sol-gel approach to the development of forensic blood substitutes: design considerations for research and training

    Year: 2017, 2017
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Stotesbury, Theresa E., Thesis advisor (ths): Wilson, Paul, Thesis advisor (ths): Vreugdenhil, Andrew, Degree committee member (dgc): Illes, Mike, Degree committee member (dgc): Easton, Brad, Degree granting institution (dgg): Trent University
    Abstract: <p>The research and development of synthetic blood substitutes is a reported need within the forensic community. This work contributes to the growing body of knowledge in bloodstain pattern analysis by offering a materials science approach to designing, producing and testing synthetic forensic blood substitutes. A key deliverable from this research is the creation of a robust silicon-based… more
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    A Model for the Differential Susceptibility of Strontium Titanate

    Year: 2016, 2016
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Lafleur, Patrick, Thesis advisor (ths): Atkinson, Bill, Degree committee member (dgc): de Haan, Hendrick, Degree committee member (dgc): Slepkov, Aaron, Degree granting institution (dgg): Trent University
    Abstract: <p>The appearance of a two-dimensional electron gas (2DEG) in oxide interfaces between strontium titanate (STO) and other materials has become a major area of study. The behaviour of the 2DEG in STO is not well understood in part because the dielectric properties of STO are not well characterized. The differential susceptibility has a major impact on the electric fields within strontium… more
    Full Text: A Model for the Differential Susceptibility of Strontium Titanate A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Master of Science in the Faculty of Art and Science Trent University …

    Mitigating Cold Flow Problems of Biodiesel: Strategies with Additives

    Year: 2016, 2016
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Mohanan, Athira, Thesis advisor (ths): NARINE, SURESH S, Degree committee member (dgc): Atkinson, Bill, Degree committee member (dgc): Chkrebtii, Anatoli, Degree granting institution (dgg): Trent University
    Abstract: <p>The present thesis explores the cold flow properties of biodiesel and the effect of vegetable oil derived compounds on the crystallization path as well as the mechanisms at play at different stages and length scales. Model systems including triacylglycerol (TAG) oils and their derivatives, and a polymer were tested with biodiesel. The goal was to acquire the fundamental knowledge that… more
    Full Text: MITIGATING COLD FLOW PROBLEMS OF BIODIESEL: STRATEGIES WITH ADDITIVES A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Doctor of Philosophy in the Faculty of Arts and Science TRENT UNIVERSITY …

    Synthesis of Lipid Based Polyols from 1-butene Metathesized Palm Oil for Use in Polyurethane Foam Applications

    Year: 2016, 2016
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Sasidharan Pillai, Prasanth Kumar, Thesis advisor (ths): NARINE, SURESH S, Degree committee member (dgc): Vreugdenhil, Andrew, Degree committee member (dgc): Rivzi, Ghaus, Degree granting institution (dgg): Trent University
    Abstract: <p>This thesis explores the use of 1-butene cross metathesized palm oil (PMTAG) as a feedstock for preparation of polyols which can be used to prepare rigid and flexible polyurethane foams. PMTAG is advantageous over its precursor feedstock, palm oil, for synthesizing polyols, especially for the preparation of rigid foams, because of the reduction of dangling chain effects associated with… more
    Full Text: Synthesis of Lipid Based Polyols from 1-butene Metathesized Palm Oil for Use in Polyurethane Foam Applications A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Doctor of Philosophy in the Faculty …

    Novel Aliphatic Lipid-Based Diesters for use in Lubricant Formulations: Structure Property Investigations

    Year: 2016, 2016
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Raghunanan, Latchmi Cindy, Thesis advisor (ths): NARINE, SURESH S, Degree committee member (dgc): Vreugdenhil, Andrew, Degree committee member (dgc): Desaulniers, Jean-Paul, Degree granting institution (dgg): Trent University
    Abstract: <p>Structure-property relationships are increasingly valued for the identification of specifically engineered materials with properties optimized for targeted application(s). In this work, linear and branched diesters for use in lubricant formulations are prepared from lipid-based oleochemicals and their structure-property relationships reported. It is shown that the branched diesters… more
    Full Text: NOVEL ALIPHATIC LIPID-BASED DIESTERS FOR USE IN LUBRICANT FORMULATIONS: STRUCTURE PROPERTY INVESTIGATIONS A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy in the …

    Novel Functional Materials From Renewable Lipids: Amphiphilic Antimicrobial Polymers and Latent Heat Thermal Energy Storage

    Year: 2015, 2015
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Floros, Michael Christopher, Thesis advisor (ths): NARINE, SURESH S, Degree committee member (dgc): Rafferty, Steve, Degree committee member (dgc): Bolshan, Yuri, Degree granting institution (dgg): Trent University
    Abstract: <p>Vegetable oils represent an ideal and renewable feedstock for the synthesis of a variety of functional materials. However, without financial incentive or unique applications motivating a switch, commercial products continue to be manufactured from petrochemical resources. Two different families of high value, functional materials synthesized from vegetable oils were studied. These… more
    Full Text: NOVEL FUNCTIONAL MATERIALS FROM RENEWABLE LIPIDS: AMPHIPHILIC ANTIMICROBIAL POLYMERS AND LATENT HEAT THERMAL ENERGY STORAGE A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Doctor of …

    Correlating density of states features with localization strength in disordered interacting systems

    Year: 2015, 2015
    Member of: Trent University Graduate Thesis Collection
    Name(s): Creator (cre): Perera, Jayanayana Lakmali, Thesis advisor (ths): Wortis, Rachel, Degree committee member (dgc): Atkinson, Bill, Degree granting institution (dgg): Trent University
    Abstract: <p>Johri and Bhatt found singular behavior near the band edge in the density of states as well as in the inverse participation ratio of the Anderson model. These singularities mark a transition to an energy range dominated by resonant states. We study the interacting case using an ensemble of two-site Anderson-Hubbard systems. We find the ensemble-averaged density of states and generalized… more
    Full Text: Correlating density of states features with localization strength in disordered interacting systems A Thesis Submitted to the Committee on Graduate Studies in Partial Fulfillment of the Requirements for the Degree of Master of Science in the Faculty of …