Trent University

Dissolved organic matter (DOM) in oceans provides nutrients and ultraviolet radiation protection to microbes. Some DOM compounds can chelate with metals, including copper, controlling their transport and bioavailability in marine systems. As copper functions as both a nutrient and toxicant, studies into the chemical structures of Cu-ligands is important, however currently limited. In this thesis, the chemical composition of total and Cu-binding DOM is investigated using Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) in the Canadian Arctic and North Pacific. Chapter 2 reveals chemical differences in DOM composition between the southern and northern Canada Basin, revealing the influence of terrestrial and biological sources. Chapter 3 shows the uniqueness of Cu-binding ligands found in the Canadian Arctic and North Pacific Ocean. Studying the composition of DOM gives insight into the chemical diversity of marine DOM, helping to predict the effects of a changing climate on marine ecosystems.

Author Keywords: biological, dissolved organic matter, fluorescence, immobilized metal-ion affinity chromatography, mass spectrometry, terrestrial

This study provides important perspectives and guidance for educators in Ontario to assist in integrating Indigenous content into public education programs – both in schools and other community educational settings. It explores how Indigenous worldviews provide unique insights for holistic education and learning how to live sustainably in place. The study also focuses on approaches to education, comparing Eurocentric and Indigenous philosophies and pedagogies, as indicators of differing value systems. Through a combination of literature review and personal interviews with eleven influential Indigenous and non-Indigenous educators in the Peterborough area, the study explores the potential for Indigenous perspectives to enhance the wellbeing and personal learning journey of all students, regardless of their backgrounds. The research concludes with recommendations for educators on how to begin integrating Indigenous Knowledge throughout programming in appropriate, respectful ways that celebrate diversity, develop positive relationships and build healthier, more sustainable communities.

Author Keywords: Education, Environment, Indigenous Knowledge, Pedagogy, Reconciliation, Worldviews

This study explored teacher infusion of Indigenous curriculum content through interviews with ten non-Indigenous teachers of social studies and history. The interviews centered on teacher perceptions of preparedness to implement Ontario's recent TRC curriculum revisions, which include more about the contributions, histories, cultures, and perspectives of Indigenous peoples. A brief analysis of Ontario's First Nation, Métis, and Inuit Education Policy Framework is included, alongside critiques of the Eurocentrism at the heart of education systems. The interviews revealed that many of the teachers were committed to Indigenous education and learning more, but they felt unprepared and lacked resources to teach Indigenous curriculum content with confidence. This study highlighted the critical role of settler teachers in Indigenous education and the importance of teachers undertaking settler unsettling in order to be effective and appropriate in Indigenous curriculum delivery. Individual changes must occur alongside educational system decolonization with a particular focus on teacher preparation.

Author Keywords: cognitive imperialism, Indigenous Education, Ontario, settler educator, settler unsettling, TRC curriculum

Deep Neural Networks (DNNs) have reached human-level performance in numerous tasks in the domain of computer vision. DNNs are efficient for both classification and the more complex task of image segmentation. These networks are typically trained on thousands of images, which are often hand-labelled by domain experts. This bottleneck creates a promising research area: training accurate segmentation networks with fewer labelled samples.

This thesis explores effective methods for learning deep representations from unlabelled images. We train a Restorative Autoencoder Network (RAN) to denoise synthetically corrupted images. The weights of the RAN are then fine-tuned on a labelled dataset from the same domain for image segmentation.

We use three different segmentation datasets to evaluate our methods. In our experiments, we demonstrate that through our methods, only a fraction of data is required to achieve the same accuracy as a network trained with a large labelled dataset.

Author Keywords: deep learning, image segmentation, representation learning, transfer learning

The risks and benefits of sexting within an intimate relationship were explored. The present study focused on sexual gratification, relationship benefits, and sexual communication as benefits and risky sexual behaviour, unethical forwarding, and infidelity as risks. A cross-sectional online survey of both undergraduate students and a community sample was used. Results indicated that sexual gratification, relationship benefits (sexual and relationship satisfaction, relationship quality, and commitment), and sexual communication are related to sexting. It appears that risky sexual behaviour is not associated with sexting, instead those who sext frequently engage in more safer sex behaviours than those who sext infrequently. Unethical forwarding does not appear to happen very often in the context of intimate relationships. Lastly, the current research indicates that some participants are sexting secondary partners, and many consider sexting secondary partners infidelity. These results show that there are both risks and benefits of sexting, which can be used to develop sext education and therapeutic programs.

Author Keywords: infidelity, relationship benefits, Sexting, sexual behaviour, sexual communication, sexual gratification

Stone axes and adzes first appeared in the eastern Gobi Desert at 8.0 cal BP and were incorporated into the technological package. At the same time, changes in local ecological conditions reflect a transition from continuous grass/shrub-steppe across the Mongolian Plateau to the development of dispersed patches of dune-field wetland oases and high-elevation forests. This thesis focuses on exploring the adoption and function of axes and adzes in the eastern Gobi Desert and their relationship to the development of these new forested ecologies. Using an experimental and use-wear approach, I analyze 29 axes and adzes from four sites in the eastern Gobi Desert of Mongolia and Inner Mongolia. Results indicate that axes and adzes were primarily used for woodworking but include other activities. Furthermore, the adoption and manufacture of axes and adzes represent an increasing investment in producing formal technologies as resources within these new diverse ecological patches were intensively utilized.

Author Keywords: Adaptation, Axes and Adzes, Eastern Gobi Desert, Neolithic, Technological Intensification, Use-Wear

The use of threats to feelings of intimacy and belonging, also known as

relational aggression, has been previously explained using attachment representations

and attributions in childhood. However, the combined role of attachment

representations and attributions in explaining relational aggression in adult peer and

romantic relationships has been unexplored. This study tested the associations

between attachment, attributions, and relational aggression with a specific focus on the

mediating role of attributions. A final sample of 258 undergraduate university

students completed self-report surveys and vignettes to measure the variables of

interest. Results suggested that attachment predicted relational aggression but, with

one exception, attributions did not explain unique variance in relational aggression

after controlling for attachment. Interestingly, hostile attributions mediated the

relationship between dismissing attachment to romantic partners and romantic

relational aggression. Therefore, individuals' attachment representations directly

influenced their levels of relational aggression in relationships regardless of their

attributions.

Author Keywords: Adulthood, Attachment, Attributions, Mediation, Relational Aggression

Historically, entrances have been used for passage between two separate temperature environments, such as moving from inside to outside of a building. Energy loss through entrances is a cause for concern, as it has been known to increase energy consumption to replace the lost energy; and with the exchange of air masses and cold air entering the building, human discomfort may occur. In this research, thermal efficiency and air circulation within a Conventional Entrance (CE) and Climate Controlled Passage (CCP) are compared.

A small scale model of the CE and CCP was constructed to examine forty-eight energy exchange conditions, emulating those found through an entrance between a temperature controlled lab and the model. Instruments such as a power meter, a flow explorer laser Doppler anemometer, and thermocouples were used to measure and compare the energy consumption, velocity vectors, and temperature energy within the entrance.

Results indicate that the CCP did retain thermal energy compared to the CE. The CE developed sloped isotherm lines and air flow that enabled and maintained thermal exhaust. Conversely, the CCP developed horizontal isotherm lines and a two-layer density current to recirculate and retain thermal energy. The research demonstrates that it is possible to increase energy efficiency of entrances in many applications.

Author Keywords: Air Recirculation, Building, Entrance, Oven, Thermal Energy Efficiency, Two-layer Density Current

Water balance models calculate water storage and movement within drainage basins, a primary concern for many hydrologists. A Thornthwaite water balance model (H2OBAAS) has shown poor accuracy in predicting low flows in the Petawawa River basin in Ontario, so lake storage and winter snow processes were investigated to improve the accuracy of the model. Lake storage coefficients, represented by the slopes of lake stage vs. lake runoff relationships, were estimated for 19 lakes in the Petawawa River basin and compared on a seasonal and inter-lake basis to determine the factors controlling lake runoff behaviour. Storage coefficients varied between seasons, with spring having the highest coefficients, summer and fall having equal magnitude, and winter having the lowest coefficients. Storage coefficients showed positive correlation with lake watershed area, and negative correlation with lake surface area during summer, fall, and winter. Lake storage was integrated into the H2OBAAS and improved model accuracy, especially in late summer, with large increases in LogNSE, a statistical measure sensitive to low flows. However, varying storage coefficients with respect to seasonal lake storage, watershed area, and surface area did not improve runoff predictions in the model. Modified precipitation partitioning and snowmelt methods using monthly minimum and maximum temperatures were incorporated into the H2OBAAS and compared to the original methods, which used only average temperatures. Methods using temperature extremes greatly improved simulations of winter runoff and snow water equivalent, with the precipitation partitioning threshold being the most important model parameter. This study provides methods for improving low flow accuracy in a monthly water balance model through the incorporation of simple snow processes and lake storages.

Author Keywords: Lake Storage, Model Calibration, Monthly Water Balance, Petawawa River, Precipitation Partitioning, Snow Melt

Mild sauna dehydration and fluid abstinence were investigated as weight loss strategies for lightweight rowers. Rowers (N=12) performed a power test, an incremental VO2max test, and a visuomotor battery: once euhydrated, once following sauna dehydration (SAU), and once following fluid abstinence and then sauna dehydration (FA). The percent body mass change (%BMC) achieved, %BMC attributable to sauna dehydration, and %BMC attributable to fluid abstinence were used within linear mixed effects models to predict hydration and performance variables. Sauna and overnight dehydration exerted indistinguishable effects on plasma osmolality, urine osmolality and thirst (p > .05). Fluid abstinence but not sauna dehydration was related to lower power production on the power test (b = 12.14W / 1%BMC, FA = 673.46 ± 79.50, SAU = 683.33 ± 72.08, p = .029), a lower total wattage produced on the incremental VO2max test (b = 4261.51W / 1%BMC, FA = 71029.58 ± 16256.56, SAU = 74001.50 ± 14936.56, p = .006), lower wattages at 2 mmol/L (b = 27.84W / 1%BMC, FA = 180.74 ± 40.27, SAU = 190.82 ± 50.79, p < .001) and 4 mmol/L (b = 20.45W / 1%BMC, FA = 221.90 ± 52.62, SAU = 238.89 ± 40.78, p = .002) blood lactate, and slower movement time on a visuomotor task (b = -38.06ms / 1%BMC, p = .004). Mild fluid abstinence but not sauna dehydration reduces rowing performance when two-hour rehydration is allowed.

Author Keywords: crew, fluid, hydration, lightweight, sauna, weight