eng

From ca. 800-1400 CE, low-density agrarian states dominated Southeast Asia,

their authority emanating from their epicentres at places such as Angkor in Cambodia,

Bagan in Myanmar, and Sukhothai in Thailand. These epicentres were the setting for

numerous structures, activities, and stakeholders that became integral for the perpetuation

of the state. These states and their epicentres declined and collapsed around the same

time. As part of a larger project (the Socio-ecological Entanglement in Tropical Societies

(SETS Project), the aim of this thesis is to add to our understanding of entanglement,

resilience, and collapse in Southeast Asia. Using a relatively new method that combines

resilience and entanglement theories, this thesis presents a view of epicentral

entanglements and vulnerabilities that eventually contributed to the collapse of these

societies. The results indicate that overextended socio-ecological systems and their

growing entanglements created a loss of resilience and, when faced with change in these

systems, collapse.

Author Keywords: Angkor, Bagan, Entanglement Theory, Resilience Theory, Southeast Asia, Sukhothai

This thesis explores the use of 1-butene cross metathesized palm oil (PMTAG) as a feedstock for preparation of polyols which can be used to prepare rigid and flexible polyurethane foams. PMTAG is advantageous over its precursor feedstock, palm oil, for synthesizing polyols, especially for the preparation of rigid foams, because of the reduction of dangling chain effects associated with the omega unsaturated fatty acids. 1-butene cross metathesis results in shortening of the unsaturated fatty acid moieties, with approximately half of the unsaturated fatty acids assuming terminal double bonds. It was shown that the associated terminal OH groups introduced through epoxidation and hydroxylation result in rigid foams with a compressive strength approximately 2.5 times higher than that of rigid foams from palm and soybean oil polyols. Up to 1.5 times improvement in the compressive strength value of the rigid foams from the PMTAG polyol was further obtained following dry and/or solvent assisted fractionation of PMTAG in order to reduce the dangling chain effects associated with the saturated components of the PMTAG. Flexible foams with excellent recovery was achieved from the polyols of PMTAG and the high olein fraction of PMTAG indicating that these bio-derived polyurethane foams may be suitable for flexible foam applications. PMTAG polyols with controlled OH values prepared via an optimized green solvent free synthetic strategy provided flexible foams with lower compressive strength and higher recovery; i.e., better flexible foam potential compared to the PMTAG derived foams with non-controlled OH values. Overall, this study has revealed that the dangling chain issues of vegetable oils can be addressed in part using appropriate chemical and physical modification techniques such as cross metathesis and fractionation, respectively. In fact, the rigidity and the compressive strength of the polyurethane foams were in very close agreement with the percentage of terminal hydroxyl and OH value of the polyol. The results obtained from the study can be used to convert PMTAG like materials into industrially valuable materials.

Author Keywords: Compressive Strength, Cross Metathesis, Fractionation, Polyols, Polyurethane Foams, Vegetable Oils

The present thesis explores the cold flow properties of biodiesel and the effect of vegetable oil derived compounds on the crystallization path as well as the mechanisms at play at different stages and length scales. Model systems including triacylglycerol (TAG) oils and their derivatives, and a polymer were tested with biodiesel. The goal was to acquire the fundamental knowledge that would help design cold flow improver (CFI) additives that would address effectively and simultaneously the flow problems of biodiesel, particularly the cloud point (CP) and pour point (PP). The compounds were revealed to be fundamentally vegetable oil crystallization modifiers (VOCM) and the polymer was confirmed to be a pour point depressant (PPD).

The results obtained with the VOCMs indicate that two cis-unsaturated moieties combined with a trans-/saturated fatty acid is a critical structural architecture for depressing the crystallization onset by a mechanism wherein while the straight chain promotes a first packing with the linear saturated FAMEs, the kinked moieties prevent further crystallization. The study of model binary systems made of a VOCM and a saturated FAME with DSC, XRD and PLM provided a complete phase diagram including the thermal transformation lines, crystal structure and microstructure that impact the phase composition along the different crystallization stages, and elicited the competing effects of molecular mass, chain length mismatch and isomerism. The liquid-solid boundary is discussed in light of a simple thermodynamic model based on the Hildebrand equation and pair interactions.

In order to test for synergies, the PP and CP of a biodiesel (Soy1500) supplemented with several VOCM and PLMA binary cocktails were measured using a specially designed method inspired by ASTM standards. The results were impressive, the combination of additives depressed CP and PP better than any single additive. The PLM and DSC results suggest that the cocktail additives are most effective when the right molecular structure and optimal concentration are provided. The cocktail mixture achieves then tiny crystals that are prevented from aggregating for an extended temperature range. The results of the study can be directly used for the design of functional and economical CFI from vegetable oils and their derivatives.

Author Keywords: Biodiesel, Microstructure, Polymorphism, Pour point depressants, Triacylglycerol, Vegetable Oil Based Crystal Modifier

In 1945, few refugee cases were as complicated as those of the Jewish survivors of the Holocaust who found themselves stranded in defeated Germany but could neither return home due to antisemitic violence nor immigrate to most countries due to extant prewar visa restrictions. Between 1945 and 1947, some 150,000 Jews fleeing ongoing antisemitic violence joined them in American-occupied Bavaria, including thousands who had survived in the Soviet Union—a phenomenon Tony Judt has described as "surviving the peace." This thesis focuses on Föhrenwald, a United Nations refugee camp outside of Munich. It interweaves oral histories with archival materials from the United Nations and the American Joint Distribution Committee to apply Atina Grossmann's work on "close encounters" between Jews, Germans, and Americans to a single refugee camp. What emerges is a portrait of the vibrant, if transient, political, social, and educational life Jews built "in the wilderness" of Germany between 1945 and 1947.

Author Keywords: Displaced Persons, Föhrenwald, Holocaust survivors, Occupied Germany (1945–49), United Nations Relief and Rehabilitation Administration

Many print sources from 1680 to 1730 depicted bawds and witches as figures of transgressive elderly femininity. They were often described as having roughly the same anti-social behaviour, age, and gender. Both witches and bawds were seen as seducing innocents into a life of sin, associating with the

devil, and acting lustful and unmotherly. Furthermore, they were connected with Catholicism and were thought to unite sinners against English Protestant society. The physical descriptions of the witch and procuress also bore significant patterns in presenting deformity, disfigurement, smelliness, rottenness, and death, traits generally connected with elderly women. Though historians have recognized the tendency of the witch or bawd to be characterized as an old woman, none have conducted a systematic comparison of the two stereotypes. Such an analysis can offer insight about the social anxieties around aging femininity in this period.

Author Keywords: bawd, cheap print, elderly women, old age, witch, witchcraft

Because federal funding for long-term care was not included as part of Canada's publicly-funded universal health care system, provincial governments have been free to determine how much, or how little, they will rely on the for-profit sector to meet the long-term care needs of their senior populations. The proportion of beds in the for-profit sector differs in each province, demonstrating that policy approaches to this type of care have developed according to distinct provincial political contexts. In this dissertation I explain why governments in two provinces, Manitoba and Ontario, have come to rely on the proprietary sector to markedly different degrees. While in the federation Manitoba stands out for its restrained reliance on this form of care, Ontario stands out for its exceptional dependence on commercial provision. In the chapters that follow I employ an historical institutionalist framework of analysis to explain why these neighbouring provinces initially pursued different policy paths in long-term care and how these paths have been sustained over time.

Following an introductory chapter in which I explain the reasons for the marginalization of long-term care within national health policy making, I provide in-depth analysis of these case studies in policy divergence. I argue that contemporary policy differences between these neighbouring provinces cannot be understood in isolation from long-term historical processes. Focusing largely on the period from the 1960s to the 1990s, I emphasize that present differences in ownership are a reflection of the different constellation of actors, events, ideas and institutions that came together at critical junctures in time, and the lasting legacies that these early windows of opportunity for reform have had on subsequent rounds of long-term care policy-making. In each province, diverging ideas about the appropriate role of the for-profit sector in meeting the long-term care needs of an aging population rose to prominence on the political agenda. Over time, rigidities developed in each system, making it difficult for actors advocating for new directions in ownership to realize their ambitions.

In both provinces policies put in place at earlier times greatly influenced future political dynamics, altered the guiding principles of government departments and policy makers, provided incentives for different interest group formations, and led to contrasting public expectations about the proper balance of the for-profit and non-profit sectors in long-term care provision. I conclude this dissertation by arguing that its findings can contribute in important ways to present discussions about long-term care reform in Canada generally and about the future role of for-profit providers specifically.

Author Keywords: Comparative Politics, Health Policy, Historical Institutionalism, Long-Term Care, Path Dependency, Provincial Politics

I investigated biodiversity of birds and vegetation associations along the boreal-tundra ecotone in Ivvavik National Park, Yukon Territory, and breeding adaptations used by American Robins (Turdus migratorius) at high latitudes. Twenty bird species were detected over three years using point-count surveys. Densities of American Robin, Dark-eyed Juncos (Junco hyemalis), and Yellow-rumped Warbler (Dendroica coronata) had positive relationships with tree and shrub density, whereas density of White-crowned Sparrows (Zonotrichia leucophrys) was negatively related to tree density. American Robins at this latitude raised only one brood, but females laid slightly larger clutches, the young fledged earlier, and pairs experienced higher nest-success than American Robins at more southerly latitudes. American Robins selected nest sites with high vegetation volume, at both the nest-site, and the nest-patch. This study is important for the first description of the bird community at this high latitude location, and describing how a species at the northern limit of the boreal forest has adapted to living with short-breeding seasons.

Author Keywords: American Robin, Ivvavik National Park, Life History, Nest-stie selection, Northern limit

The typical contrast mechanism employed in multimodal CARS microscopy involves the use of other nonlinear imaging modalities such as two-photon excitation fluorescence (TPEF) microscopy and second harmonic generation (SHG) microscopy to produce a molecule-specific pseudocolor image. In this work, I explore the use of unsupervised multivariate statistical analysis tools such as Principal Component Analysis (PCA) and Vertex Component Analysis (VCA) to provide better contrast using the hyperspectral CARS data alone. Using simulated CARS images, I investigate the effects of the quadratic dependence of CARS signal on concentration on the pixel clustering and classification and I find that a normalization step is necessary to improve pixel color assignment. Using an atherosclerotic rabbit aorta test image, I show that the VCA algorithm provides pseudocolor contrast that is comparable to multimodal imaging, thus showing that much of the information gleaned from a multimodal approach can be sufficiently extracted from the CARS hyperspectral stack itself.

Author Keywords: Coherent Anti-Stokes Raman Scattering Microscopy, Hyperspectral Imaging, Multimodal Imaging, Multivariate Analysis, Principal Component Analysis, Vertex Component Analysis

The relationship between siblings is unique in both its history and duration across the lifespan. Previous relationship researchers have examined siblings in childhood, but few have explored this distinctive relationship in adulthood. In this study, the adult sibling relationship was explored from an attachment perspective to determine the effect of an individual's attachment on conflict and collaboration with siblings. As expected, secure attachment predicted negative associations with conflict and positive associations with collaboration whereas insecure attachment (fearful, preoccupied, and dismissing) predicted opposite patterns. Results were compared to the abundance of literature on romantic relationships and findings from this study provided support for the theory that siblings function as attachment figures in adulthood.

Author Keywords: Attachment, Collaboration, Conflict, Relationships, Romantic partners, Siblings

My study was primarily focused on the comparison of life history traits between stocked American eel and their naturally recruited conspecifics in Lake Ontario and the upper St. Lawrence River (USLR/LO). I found that stocked eels experienced faster annual growth than their naturally recruited conspecifics and were comprised of a greater proportion of males. These findings indicate that the life history patterns of American eel may be genetically predisposed. Additionally, my study served to characterize the diets of stocked American eel and examine possible associations between eel and prey size. The eels consumed a number of macroinvertebrate prey orders as well as fishes and macrocrustaceans, with the latter prey items being more prevalent in the diets of larger eel specimens. A disparity in eel growth and body condition was observed between two primary stocking locations and were likely attributable to differences in available forage and habitat. Lastly, growth, body condition, and stocked eel diet were compared between lentic and lotic habitats. Eels from lotic streams experienced slower annual growth and had reduced body condition, and their diets were comprised of smaller prey items. The results of this study suggest that the current stocking methods employed in the USLR/LO are not suitable to restore the natural recruitment of individuals that will exhibit desired life history traits.