Trent University

The present thesis entails a qualitative investigation of the unique notion to transition media change from the current paper-based system to the potential use of information technology innovation for communication between health care providers and employers during return to work. Stakeholder perspectives on relevant communication phenomena were gathered from workers, employers, and health care providers with experience in return to work. Methods for analysis involved critical realist grounded theory, as well as the use of a prototype innovation, named the Return to Work Expert App, as a platform for participant evaluation and discourse. The study's findings provided comprehensive and in-depth understanding of return to work communication, beyond its empirical regularities. The generative mechanisms of common communication problems that were discovered included situated reasoning, media as information ("the medium is the message"), epistemological disjuncture, egoism-altruism-collectivism quandary, and perspective taking. A novel theoretical framework based on ecological psychology was also advanced to offer a coherent and systematic understanding of the situated nature of health care providers' reasoning and information development. Media change via the Return to Work Expert App was argued to be limited in handling and resolving many of the communication problems that can occur. However, the app had perceptible value and benefits to prospective users that suggested a distinct advantage over current paper-based practices. Opportunities for further development and research exist to address relevant challenges, most notable of all being the need to address the app's burden of proof. For the interested reader, this thesis advances research and knowledge of provider-employer communication to a state that is truly fitting of the importance acknowledged of it in the field of return to work.

Author Keywords: critical realism, ecological psychology, media change, return to work, stakeholder communication, technological acceptance

Online behavioural advertising (OBA) is an advertising technique which relies on collected customer information and online activity to serve people with more relevant ads. On November 16th, 2013, Bell Canada launched their first OBA program via Bell Mobility: the Bell Targeted Ads Program, or BTAP. My thesis provides an ethical analysis of BTAP and shows that Bell undermined and violated customer privacy, stifled customer autonomy, and harmed customer identity. Relevant moral problems include typification, a disrespecting of customer autonomy, and identity commodification.

I show that BTAP was unethical by grounding my arguments within the moral framework of Information Ethics (IE). IE is an ethical system which focuses on the role of information in the ethical dilemmas. IE also justifies the self-constitutive theory of privacy (SCP) which argues that our information and privacy are entangled with our identities. This gives us strong reason to defend our privacy/identity within BTAP.

After making several arguments which demonstrate that BTAP was unethical, I will then turn my attention to showing how it is possible to rectify and mitigate many of BTAP's ethical problems by installing a two-stage opt-in (TSOI) which provides customers with a greater deal of autonomy, and the ability to remove themselves from BTAP.

Author Keywords: Bell Canada, Ethics, Identity, Online Behavioural Advertising, Privacy, Targeted Advertising

Evidence suggests that visuomotor system behaviour may be more sensitive to the prolonged effects of mild brain injuries than neuropsychological tests. We evaluated whether participants with a mild closed head injury (CHI) would show lingering visuomotor deficits, but not cognitive deficits, up to three years post-injury compared to participants with an orthopaedic injury and healthy controls. All three groups completed a tablet-based visuomotor assessment tool and a brief neuropsychological test battery. The CHI participants scored comparable to the control groups on the neuropsychological tests, but when assessed for visuomotor function requiring adjustment to a changing stimulus, CHI participants showed poorer performance than the control groups. Combined, these findings add to the evidence that CHI can lead to persistent visuomotor deficits that extend beyond those of neuropsychological tests. Therefore, visuomotor assessment should be included in brain injury and recovery evaluation, and this can be accomplished easily using tablet-based tasks.

Author Keywords: closed head injury, neuropsychological assessment, recovery, tablet, traumatic brain injury, visuomotor

Activated Carbon (AC) is commonly produced by gasification, but there has been increasing interest in chemical activation due to its lower activation temperatures and higher yields. Phosphoric acid, in particular, succeeds in both these areas. Phosphoric acid activated carbon (PAC) can be environmentally sustainable, and economically favourable, when the phosphoric acid used in the activation is recycled. This thesis describes the digestion and activation of waste wood using phosphoric acid, as well as methods used to recover phosphoric acid, functionalize the produced activated carbon with iron salts and then test their efficacy on the adsorption of target analytes, selenite and selenate. In order to achieve an efficient phosphoric acid based chemical activation, further understanding of the activation process is needed. A two-step phosphoric acid activation process with waste wood feed stock was examined. The filtrate washes of the crude product and the surface composition of the produced PAC were characterized using X-ray Photoelectron Spectroscopy (XPS), Fourier Transform-Infrared spectroscopy (FT-IR), Ion Chromatography (IC), and 31P Nuclear Magnetic Resonance (NMR). XPS of the unwashed PAC contained 13.3 atomic percent phosphorous, as phosphoric acid, while the washed sample contained 1.4 atomic percent phosphorous as PO43-, and P2O74-. Using 31P NMR, phosphoric acid was identified as the primary phosphorous species in the acidic 0.1 M HCl washings, with pyrophosphates also appearing in the second 0.1 M NaOH neutralizing wash, and finally a weak signal from phosphates with an alkyl component also appearing in the DI wash. IC showed high concentrations of phosphoric acid in the 0.1 M HCl wash with progressively lower concentrations in both the NaOH and DI washes. Total phosphoric acid recovery was 96.7 % for waste wood activated with 25 % phosphoric acid, which is higher than previous literature findings for phosphoric acid activation. The surface areas of the PAC were in the 1500-1900 m2g-1 range. Both pre and post activation impregnation of iron salts resulted in iron uptake. Pre-activation resulted in only iron(III) speciation while post-activation impregnation of iron(II)chloride did result in iron(II) forming on the PAC surface. The pre-activated impregnated PAC showed little to no adsorption of selenite and selenate. The post-activation impregnated iron(II)chloride removed up to 12.45 ± 0.025 mg selenium per g Iron-PAC. Competitive ions such as sulfate and nitrate had little effect on selenium adsorption. Phosphate concentration did affect the uptake. At 250 ppm approximately 75 % of adsorption capacity of both the selenate and the selenite solutions was lost, although selenium was still preferentially adsorbed. Peak adsorption occurred between a pH of 4 and 11, with a complete loss of adsorption at a pH of 13.

Author Keywords: Activated Carbon, doping, Iron, phosphoric acid, selenium

The Air Health Trend Indicator (AHTI) is a joint Health Canada / Environment and Climate Change Canada initiative that seeks to model the Canadian national population health risk due to acute exposure to ambient air pollution. The common model in the field uses averages of local ambient air pollution monitors to produce a population-level exposure proxy variable. This method is applied to ozone, nitrogen dioxide, particulate matter, and other similar air pollutants.

We examine the representative nature of these proxy averages on a large-scale Canadian data set, representing hundreds of monitors and dozens of city-level populations. The careful determination of temporal and spatial correlations between the disparate monitors allows for more precise estimation of population-level exposure, taking inspiration from the land-use regression models commonly used in geography. We conclude this work with an examination of the risk estimation differences between the original, simplistic population exposure metric and our new, revised metric.

Author Keywords: Air Pollution, Population Health Risk, Spatial Process, Spatio-Temporal, Temporal Process, Time Series

The spatial and temporal variation in atmospheric nitrogen dioxide (NO2), ammonia (NH3), and 17 elements (V, Cr, Fe, Ni, Cu, Zn, As, Cd, Pb, Mg, Al, Ca, Co, Se, Sb, Mn, and Na) were measured at 40 road side locations along a ~250 km traffic density gradient of 40,000–400,000 vehicles on the King's Highway 401, in Ontario, Canada. Elemental concentrations were measured over a year, using moss bags as passive samplers, for four quarterly three-month exposure periods (October 2015 – October 2016). Gaseous NO2 and NH3 concentrations were measured using Willem's badge passive diffusive samplers for twelve one-week exposure periods (one per month: October 2015–October 2016). Dry deposition of nitrogen was estimated using the inferential method. There were significant linear relationships between NO2 and NH3 and average annual daily traffic (AADT) volumes across the study area; higher concentrations corresponded to higher volume traffic sites. Average NO2 concentrations at sites ranged from 23.5 to 73 μg/m3, with an annual average of 43.7 μg/m3. Ammonia ranged from 2.56 to 13.55 μg/m3, with an annual average of 6.44 μg/m3. There were significant quarterly variations in NO2, with concentrations peaking during the winter months. In contrast, NH3 showed no significant quarterly variation, but a slight peak occurred during the summer. Gaseous NO2 and NH3 were highly positively correlated (r = 0.63), suggesting a common emission source from traffic. Concentrations in exposed moss were determined by subtracting the total concentration of each metal in the exposed sample from the background concentration present in the moss. Relative accumulation factors (RAF) and contamination factors were also calculated to determine the anthropogenic influence on tissue concentrations in exposed moss. All metals showed elevated levels versus background concentrations, with all metals except Ni and Co showing considerable enrichment. The highest levels of contamination were from V, Cr, Fe, Zn, Cd, Sb, Pb and Na. Principal component analysis indicated 5 clear clusters of related elements, with PC1 accounting for 36.2% and PC2 accounting for 25.6% of the variance. Average annual daily traffic was significantly related to Cr, Fe, Cu, Sb, Mn, Al, and Na. Road side monitoring shows consistently higher concentrations than active monitoring sites located further from the edge of the road, indicating a need for increased road side monitoring in Ontario, Canada.

It is well-established that alexithymia in adulthood is a critical risk factor for numerous negative mental health and well-being outcomes. Although this area of research has begun to receive interest in earlier developmental stages, significant methodological limitations have been noted with current measures of alexithymia for adolescence. As such, the aim of the current thesis was to provide empirical evidence on the psychometric strength of a new adolescent measure of alexithymia, the Toronto Alexithymia Scale – Adolescent Version (TAS-A). Study 1 examined the construct validity of the TAS-A in relation to self and informant reported emotional intelligence (EI), while study 2 examined the predictive validity of the TAS-A in relation to adolescent problematic gambling and academic achievement. Adolescents completed self-reports of alexithymia, EI, and gambling behaviour, parents completed informant reports regarding their child's EI, and academic records were obtained. Confirmatory factor analyses revealed significant relationships between adolescent alexithymia, and self and informant reported EI, indicating significant overlap in constructs. Adolescent alexithymia was also shown to be a significant predictor of problematic gambling and academic achievement; however, some interesting gender differences were observed (a pattern of results reported consistently in the adult alexithymia literature). Results are discussed in terms of methodological and clinical implications during the vulnerable developmental transition of adolescence.

Author Keywords: adolescence, alexithymia, psychometrics

According to the Invasional Meltdown Hypothesis (IMH), invasive species may interact in their introduced range and facilitate future invasions. This study investigated the possibility that Alliaria petiolata, an invasive allelopathic herbaceous plant in Ontario, is facilitating invasions by additional alien species. Two allelopathic focal species were chosen for this study: the native Solidago canadensis and the invasive A. petiolata. Field surveys in southern Ontario that quantified plant biodiversity in plots that included one or both focal species revealed no support for the IMH, although fewer species co-existed with A. petiolata than with S. canadensis. A year-long recruitment experiment in Peterborough, Ontario, also produced results inconsistent with the IMH, although did provide some evidence that A. petiolata limited recruitment of other species. These results collectively show negative impacts on regional biodiversity by A. petiolata, even in the absence of an invasional meltdown.

Author Keywords: allelopathy, Alliaria petiolata, co-occurrence surveys, invasional meltdown hypothesis, invasive species, Solidago canadensis

Typically task interference is studied using reaching adaptation tasks (visuomotor rotation and/or force-field learning). Participants in these experiments are already experts at the base task (point-to-point, planar reaching) and their ability to adapt reaching to the imposed perturbation is studied. The pattern of data induced by the perturbation is used to make inferences about the nature and neural correlates of our learning and memory for reaching perturbations, specifically, and motor performance in general. We wanted to see if it is possible to demonstrate this same interference pattern using a novel vegetable-chopping task, where we can easily recreate natural performance settings using a task for which we can easily identify non-experts. Participants performed a chopping task in which they are asked to chop a sweet potato into 5 mm-wide slices, matching the beat of a metronome (120 bpm). Following this initial learning, participants were exposed to an interference condition. Participants then performed trials of the original task again. Interference was inferred if the second performance of the original task was impaired, compared to initial performance. Experiment 1 involved novice choppers, and either the force or frequency of chops was manipulated. Only the altered frequency task produced interference effects. In Experiment 2, competent and expert choppers had to manage either a faster or slower frequency. We found evidence for interference in competents, but not experts. These results support the idea that the vulnerability to interference of motor memory changes with practice, and so any inferences made about memory structure must take into account not only expert performance, but every level of skill.

Author Keywords: expertise, interference, motor learning, reaching adaptation

In this thesis, I use "Trump's Wall" between Mexico and the US to resist Eurocentrism and the challenges Eurocentric pedagogy poses to the research-practitioner. In my method, I reimagine C. Alejandra Elenes' borderlands theory as a zone of empowerment within a multicultural Canadian classroom, and braid it in a hybrid assemblage with the rhizome.

The "rhizo-borderlands" assemblage uses selected field notes gleaned from my teaching practice to develop themes of a critical pedagogy of globality in personal, local and international dimensions. These are further braided with a "day-in-the-life" narrative of a fictionalized student (Ellie) who navigates her way towards a world literature classroom where the focus is The Kite Runner by Khaled Hosseini.

This assemblage affirms my belief that teaching and learning provides a context where students become "border crossers" and navigate points of intersection between their local and global selves, in order to develop intercultural competencies.

Author Keywords: Action Narrative, Critical Pedagogy, Rhizomes